tris(2-methylphenyl)[(trifluoromethanesulfonyl)imino]-λ5-stibane

Base Information

• Chemical Name: tris(2-methylphenyl)[(trifluoromethanesulfonyl)imino]-λ5-stibane
• CAS No.: 264282-83-9
• Molecular Formula: C₂₂H₂₁F₃NO₂SSb
• Molecular Weight: 542.225
• Mol file: 264282-83-9.mol

Synonyms:tris(2-methylphenyl)[(trifluoromethanesulfonyl)imino]-λ5-stibane

Chemical Property of tris(2-methylphenyl)[(trifluoromethanesulfonyl)imino]-λ5-stibane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of tris(2-methylphenyl)[(trifluoromethanesulfonyl)imino]-λ5-stibane

There total 2 articles about tris(2-methylphenyl)[(trifluoromethanesulfonyl)imino]-λ5-stibane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

(C6H4CH3)3SbCl2 (52762-60-4) + Trifluoromethanesulfonamide (421-85-2) → tris(2-methylphenyl)[(trifluoromethanesulfonyl)imino]-λ5-stibane (264282-83-9)

Guidance literature:

With potassium tert-butylate; In dichloromethane; react. of Sb compd. with CF3SO2NH2 in CH2Cl2 soln. in the presence of KO-t-Bu (2.2 equiv.); from -50°C to room temp.;

DOI:10.1021/ic991120e

Reference yield: 90.0%

Trifluoromethanesulfonamide (421-85-2) + tri(o-tolyl)antimony (23822-15-3) → tris(2-methylphenyl)[(trifluoromethanesulfonyl)imino]-λ5-stibane (264282-83-9)

Guidance literature:

With diethylazodicarboxylate; In diethyl ether; react. of Sb compd. with CF3SO2NH2 in Et2O soln. in the presence of diethylazodicarboxylate; from 0°C to room temp.;

DOI:10.1021/ic991120e

upstream raw materials:

(C₆H₄CH₃)3SbCl₂

Trifluoromethanesulfonamide

tri(o-tolyl)antimony