23822-15-3

Usage

Uses

Used in Organic Synthesis:
Tris(2-methylphenyl)stibane serves as a reagent in organic synthesis, facilitating the formation of various complex organic molecules. Its unique stibine structure allows it to participate in a range of chemical reactions, making it a valuable component in the synthesis of pharmaceuticals, agrochemicals, and other specialty chemicals.
Used as a Catalyst:
In some chemical reactions, tris(2-methylphenyl)stibane functions as a catalyst to increase the rate of reaction without being consumed in the process. Its catalytic properties can be leveraged to enhance the efficiency of industrial processes and improve the yield of desired products.
Used in Research and Development:
Due to its unique chemical properties, tris(2-methylphenyl)stibane is utilized in research and development settings to explore new chemical pathways and investigate the behavior of organoantimony compounds in various reaction conditions.
Safety Considerations:
Given its high toxicity, tris(2-methylphenyl)stibane requires careful handling with appropriate personal protective equipment and under controlled conditions to minimize exposure. Strict adherence to proper storage and disposal protocols is essential to ensure the safety of individuals and the environment.

Upstream product

• 615-37-2 ortho-methylphenyl iodide 
• 106-38-7 para-bromotoluene 
• 95-46-5 2-methylphenyl bromide 
• 7789-61-9 antimony(III) bromide 
• 10025-91-9 antimony(III) chloride 
• 932-31-0 ortho-tolylmagnesium bromide 
• 166989-24-8 o-tolylbis(trimethylsilyl)antimony 

Downstream Products

• 6699-93-0 (2-methylphenyl)lithium 
• 382148-90-5 [(trichloroacetyl)imino]tris(2-methylphenyl)-λ5-stibane 
• 10050-08-5 tri-o-tolylbismuth 
• 91994-11-5 5,5-dimethyl-2-(o-tolyl)-1,3,2-dioxaborinane 
• 264282-83-9 tris(2-methylphenyl)[(trifluoromethanesulfonyl)imino]-λ5-stibane 
• 52748-97-7 trans-dibromobis(tri(2-methylphenyl)stibine)palladium(II) 
• 52680-45-2 trans-dichlorobis(tri(2-methylphenyl)stibine)palladium(II) 
• 174618-63-4 tris(o-tolyl)antimony dithiocyanate 
• 63288-30-2 Pd(tri-o-tolylstibine)2(SCN)2 
• 63288-32-4 Pt(tri-o-tolylstibine)2Cl₂ 

Relevant academic research and scientific papers

Oxidative Cross-Coupling of Boron and Antimony Nucleophiles via Palladium(I)

The use of an isolatable, monomeric Pd(I) complex as a catalyst for the oxidative cross-coupling of aryl-antimony and aryl-boron nucleophiles is reported. This reaction tolerates a wide variety of substrates, with >20:1 selectivity for cross-coupled products. This strategy offers a new approach to achieving the selective cross-coupling of nucleophiles.

Fourier-transform Raman and infrared spectra and normal coordinate analysis of the triphenyl compounds and their methyl-, methoxy- and fluoro-substituted derivatives of arsenic, antimony and bismuth

The Fourier transform (FT)-Raman and infrared (IR) spectra of triphenyl-, perdeuterated triphenyl-, tris(2-methylphenyl)-, tris(3-methylphenyl)-, tris(2,4,6-trimethylphenyl)-, tris(2-methoxyphenyl)-, tris(3-methoxyphenyl)-, tris(3-fluorophenyl)- and tris(

Oxygen bridged hexa(organo)di-antimony compounds: Hydrolysis by traces of moisture and crystal structures of [SbR3Br]2O, where R = p-or o-tolyl

1H and 13C NMR spectroscopy of four compounds of the type [SbR3X]2O, where X = Br and R = Ph, p-tolyl and o-tolyl or X = Cl and R = Me, have been interpreted as showing that unless stringent precautions are take

Syntheses, Structures, and Equilibria of o-, m-, p-Tolyl- and Phenylantimony Rings

Exchange reactions of R3Sb (R = o-Tol, m-Tol, p-Tol) with SbCl3 in a 1:2 molar ratio give RSbCl2.Silylstibanes RSb(SiMe3)2 were obtained by reaction of RSbCl2 and Me3SiCl with Mg in THF.Slow access of air to solutions of RSb(SiMe3)2 afforded orange crystals of the composition (RSb)n.Crystal structures were determined by X-ray crystallography fro R = o-Tol and m-Tol as stacks of (RSb)6 rings in the chair conformation with equatorial substituents.In the crystals of (m-TolSb)6 there are short intermolecular Sb***Sb distances of 420 pm.Solutions of (RSb)n (R = Ph, o-Tol, m-Tol, p-Tol) in C6D6 were analyzed by 1H-NMR spectroscopy.They contain (RSb)5 and (RSb)4 in equilibria.Raman spectra of (PhSb)6 or (p-TolSb)n show signals for Sbn at = 151 or 153 cm-1. 13C-CP-MAS-NMR data of (p-TolSb)n are reported. - Key Words: Cyclopentastibanes/ Cyclohexastibanes/ Antimony compounds/ Phenylantimony rings