methanesulfonic acid 2-(2-cyclopropoxy-5-trifluoromethoxy-phenyl)-allyl ester

Base Information

Chemical Name:methanesulfonic acid 2-(2-cyclopropoxy-5-trifluoromethoxy-phenyl)-allyl ester
CAS No.:405517-61-5
Molecular Formula:C₁₄H₁₅F₃O₅S
Molecular Weight:352.331
Hs Code.:

Synonyms:methanesulfonic acid 2-(2-cyclopropoxy-5-trifluoromethoxy-phenyl)-allyl ester

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Chemical Property of methanesulfonic acid 2-(2-cyclopropoxy-5-trifluoromethoxy-phenyl)-allyl ester

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Technology Process of methanesulfonic acid 2-(2-cyclopropoxy-5-trifluoromethoxy-phenyl)-allyl ester

There total 5 articles about methanesulfonic acid 2-(2-cyclopropoxy-5-trifluoromethoxy-phenyl)-allyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 405517-56-8
1-(vinyloxy)-2-iodo-4-trifluoromethoxybenzene

: 405517-61-5
methanesulfonic acid 2-(2-cyclopropoxy-5-trifluoromethoxy-phenyl)-allyl ester

Guidance literature:: Multi-step reaction with 5 steps

1.1: 99 percent / Et₂Zn / 1,2-dichloro-ethane / -5 - 20 °C

2.1: magnesium; methyl tert-butyl ether / 3 h / Heating

2.2: methyl tert-butyl ether / -20 - 5 °C

3.1: KOt-Bu / tetrahydrofuran / -20 - 20 °C

4.1: 5.48 g / LiI / various solvent(s) / 30 h / 100 °C

5.1: DIEA / CH₂Cl₂ / -40 °C

With tert-butyl methyl ether; potassium tert-butylate; diethylzinc; magnesium; N-ethyl-N,N-diisopropylamine; lithium iodide; In tetrahydrofuran; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1021/jo0157472

Reference yield:

: 208831-25-8
1-(cyclopropyloxy)-2-iodo-4-(trifluoromethoxy)benzene

: 405517-61-5
methanesulfonic acid 2-(2-cyclopropoxy-5-trifluoromethoxy-phenyl)-allyl ester

Guidance literature:: Multi-step reaction with 4 steps

1.1: magnesium; methyl tert-butyl ether / 3 h / Heating

1.2: methyl tert-butyl ether / -20 - 5 °C

2.1: KOt-Bu / tetrahydrofuran / -20 - 20 °C

3.1: 5.48 g / LiI / various solvent(s) / 30 h / 100 °C

4.1: DIEA / CH₂Cl₂ / -40 °C

With tert-butyl methyl ether; potassium tert-butylate; magnesium; N-ethyl-N,N-diisopropylamine; lithium iodide; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo0157472

Reference yield:

: 405517-55-7
1-(2-chloroethoxy)-2-iodo-4-trifluoromethoxybenzene

: 405517-61-5
methanesulfonic acid 2-(2-cyclopropoxy-5-trifluoromethoxy-phenyl)-allyl ester

Guidance literature:: Multi-step reaction with 6 steps

1.1: 80 percent / KOt-Bu / tetrahydrofuran / 20 h / 20 °C

2.1: 99 percent / Et₂Zn / 1,2-dichloro-ethane / -5 - 20 °C

3.1: magnesium; methyl tert-butyl ether / 3 h / Heating

3.2: methyl tert-butyl ether / -20 - 5 °C

4.1: KOt-Bu / tetrahydrofuran / -20 - 20 °C

5.1: 5.48 g / LiI / various solvent(s) / 30 h / 100 °C

6.1: DIEA / CH₂Cl₂ / -40 °C

With tert-butyl methyl ether; potassium tert-butylate; diethylzinc; magnesium; N-ethyl-N,N-diisopropylamine; lithium iodide; In tetrahydrofuran; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1021/jo0157472