4-(Iodomethyl)cyclopentene

Base Information

Chemical Name:4-(Iodomethyl)cyclopentene
CAS No.:83528-59-0
Molecular Formula:C6H9I
Molecular Weight:208.042
Hs Code.:2903890090
DSSTox Substance ID:DTXSID40376690

Synonyms:4-(iodomethyl)cyclopentene;83528-59-0;4-(IODOMETHYL)-CYCLOPENTENE;Cyclopentene,4-(iodomethyl)-;4-(iodomethyl)cyclopent-1-ene;SCHEMBL1097292;DTXSID40376690;FT-0720964

Suppliers and Price of 4-(Iodomethyl)cyclopentene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
4-(IODOMETHYL)-CYCLOPENTENE 95.00%
5MG
$ 495.86

Total 11 raw suppliers

Chemical Property of 4-(Iodomethyl)cyclopentene

Chemical Property:

Vapor Pressure:0.765mmHg at 25°C
Refractive Index:1.575
Boiling Point:190 ºC at 760 mmHg
Flash Point:78.9 ºC
PSA：0.00000
Density:1.706 g/cm³
LogP:2.38760
XLogP3:2.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:207.97490
Heavy Atom Count:7
Complexity:68.2

Purity/Quality:

97% ^*data from raw suppliers

4-(IODOMETHYL)-CYCLOPENTENE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C=CCC1CI

Technology Process of 4-(Iodomethyl)cyclopentene

There total 1 articles about 4-(Iodomethyl)cyclopentene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 25125-21-7
4-(hydroxymethyl)cyclopentene

: 83528-59-0
(3-cyclopentenyl)iodomethane

Guidance literature:: With 1H-imidazole; iodine; triphenylphosphine; In diethyl ether; acetonitrile; at 0 - 20 ℃; for 2h;
DOI:10.1002/ejoc.200300448

Reference yield:

: 83528-59-0
(3-cyclopentenyl)iodomethane

: 115119-74-9,115183-73-8
exo,exo-1,3-dichlorobicyclo<2.2.1>heptane-endo-1-nitrile

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) LDA / 1.) THF, -55 to -60 deg C; 2.) THF, HMPA, -55 to -60 deg C, 1 h, -30 deg C, 3 h

2: 87 percent / trimethyl aluminum, ammonium chloride / CH₂Cl₂ / Heating

3: 86 percent / pyridine, trifluoroacetic anhydride / tetrahydrofuran / 0 deg C, 1 h, room temp., 3h

4: 33 percent Chromat_. / CuCl, PPh₃ / benzene / 8 h / 160 - 165 °C

With pyridine; ammonium chloride; trimethylaluminum; trifluoroacetic anhydride; lithium diisopropyl amide; triphenylphosphine; copper(l) chloride; In tetrahydrofuran; dichloromethane; benzene;
DOI:10.1021/ja00224a043

Reference yield:

: 83528-59-0
(3-cyclopentenyl)iodomethane

: 115119-74-9,115183-73-8
endo,exo-1,3-dichlorobicyclo<2.2.1>heptane-exo-1-nitrile

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) LDA / 1.) THF, -55 to -60 deg C; 2.) THF, HMPA, -55 to -60 deg C, 1 h, -30 deg C, 3 h

2: 87 percent / trimethyl aluminum, ammonium chloride / CH₂Cl₂ / Heating

3: 86 percent / pyridine, trifluoroacetic anhydride / tetrahydrofuran / 0 deg C, 1 h, room temp., 3h

4: 61 percent Chromat_. / CuCl, PPh₃ / benzene / 8 h / 160 - 165 °C

With pyridine; ammonium chloride; trimethylaluminum; trifluoroacetic anhydride; lithium diisopropyl amide; triphenylphosphine; copper(l) chloride; In tetrahydrofuran; dichloromethane; benzene;
DOI:10.1021/ja00224a043