2,4-dinitro-4'-methylsulfonyldiphenyl sulfone

Base Information

• Chemical Name: 2,4-dinitro-4'-methylsulfonyldiphenyl sulfone
• CAS No.: 75317-07-6
• Molecular Formula: C₁₃H₁₀N₂O₈S₂
• Molecular Weight: 386.363
• Mol file: 75317-07-6.mol

Synonyms:2,4-dinitro-4'-methylsulfonyldiphenyl sulfone

Chemical Property of 2,4-dinitro-4'-methylsulfonyldiphenyl sulfone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,4-dinitro-4'-methylsulfonyldiphenyl sulfone

There total 6 articles about 2,4-dinitro-4'-methylsulfonyldiphenyl sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

2,4-dinitro-4'-methylsulfonyldiphenyl sulfide (86602-00-8) → 2,4-dinitro-4'-methylsulfonyldiphenyl sulfone (75317-07-6)

Guidance literature:

With dihydrogen peroxide; In acetic acid; for 6h; Heating;

Reference yield:

2,4-dinitro-4'-methylthiodiphenyl sulfide (99293-67-1) → 2,4-dinitro-4'-methylsulfonyldiphenyl sulfone (75317-07-6)

Guidance literature:

With dihydrogen peroxide; acetic acid;

Reference yield:

4-(methylsulfonyl)benzenethiol (3814-25-3) → 2,4-dinitro-4'-methylsulfonyldiphenyl sulfone (75317-07-6)

Guidance literature:

Multi-step reaction with 2 steps

1: NaHCO₃; ethanol

2: aqueous H₂O₂; acetic acid

With ethanol; dihydrogen peroxide; sodium hydrogencarbonate; acetic acid;

upstream raw materials:

2,4-dinitro-4'-methylthiodiphenyl sulfide

2,4-dinitro-4'-methylsulfonyldiphenyl sulfide

4-methanesulfonyl-benzenethiosulfonic acid S-(4-methanesulfonyl-phenyl ester)

1-chloro-2,4-dinitro-benzene

Downstream raw materials:

potassium 2,4-dinitrophenolate

Refernces

• 1、 Efremov, Yu. A.,Popova, A. G.,Khmel'nitskii, R. A.,Kaminskii, A. Ya,Fedyainov, N. V.. "VARIATION OF THE VALENCE OF SULFUR IN SUBSTITUTED 2,4-DINITROPHENYL PHENYL SULFOXIDES IN REARRANGEMENT PROCESSES". . p. 944 - 949. Retrieved 2007/10/02.