Technology Process of C36H49F3O7
There total 22 articles about C36H49F3O7 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
3-chloro-benzenecarboperoxoic acid;
In
phosphate buffer; dichloromethane;
at 20 ℃;
for 1h;
DOI:10.1016/S0040-4020(00)00878-4
- Guidance literature:
-
Multi-step reaction with 11 steps
1.1: BF3*Et2O / CH2Cl2
2.1: H2 / Pd/C / ethyl acetate
3.1: NaOMe / methanol
4.1: pyridine
5.1: DEAD; Ph3P / toluene / -15 - 20 °C
6.1: 5.4 g / NaOMe / methanol / 2 h / 20 °C
7.1: 71 percent / NaH; Bu4NI / tetrahydrofuran / 0 - 20 °C
8.1: 84 percent / TMEDA / diethyl ether / 8 h / 20 °C
9.1: O3; O2 / CH2Cl2; methanol / -78 °C
9.2: 80 percent / triphenylphosphine / CH2Cl2; methanol / 2 h / -78 - 20 °C
10.1: Na(NSiMe3)2 / toluene / 1 h / 20 °C
10.2: 84 percent / toluene / 0.75 h / -78 °C
11.1: 100 percent / m-CPBA / aq. phosphate buffer; CH2Cl2 / 1 h / 20 °C
With
pyridine; N,N,N,N,-tetramethylethylenediamine; boron trifluoride diethyl etherate; hydrogen; oxygen; sodium methylate; sodium hexamethyldisilazane; tetra-(n-butyl)ammonium iodide; sodium hydride; ozone; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; diethylazodicarboxylate;
palladium on activated charcoal;
In
tetrahydrofuran; methanol; phosphate buffer; diethyl ether; dichloromethane; ethyl acetate; toluene;
1.1: Ferrier reaction / 2.1: Hydrogenation / 3.1: Deacetylation / 4.1: Tosylation / 5.1: Mitsunobu reaction / 6.1: Hydrolysis / 7.1: Etherification / 8.1: Alkylation / 9.1: ozonolysis / 9.2: Decomposition / 10.1: deprotonation / 10.2: Wittig reaction / 11.1: Epoxidation;
DOI:10.1016/S0040-4020(00)00878-4
- Guidance literature:
-
Multi-step reaction with 10 steps
1.1: H2 / Pd/C / ethyl acetate
2.1: NaOMe / methanol
3.1: pyridine
4.1: DEAD; Ph3P / toluene / -15 - 20 °C
5.1: 5.4 g / NaOMe / methanol / 2 h / 20 °C
6.1: 71 percent / NaH; Bu4NI / tetrahydrofuran / 0 - 20 °C
7.1: 84 percent / TMEDA / diethyl ether / 8 h / 20 °C
8.1: O3; O2 / CH2Cl2; methanol / -78 °C
8.2: 80 percent / triphenylphosphine / CH2Cl2; methanol / 2 h / -78 - 20 °C
9.1: Na(NSiMe3)2 / toluene / 1 h / 20 °C
9.2: 84 percent / toluene / 0.75 h / -78 °C
10.1: 100 percent / m-CPBA / aq. phosphate buffer; CH2Cl2 / 1 h / 20 °C
With
pyridine; N,N,N,N,-tetramethylethylenediamine; hydrogen; oxygen; sodium methylate; sodium hexamethyldisilazane; tetra-(n-butyl)ammonium iodide; sodium hydride; ozone; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; diethylazodicarboxylate;
palladium on activated charcoal;
In
tetrahydrofuran; methanol; phosphate buffer; diethyl ether; dichloromethane; ethyl acetate; toluene;
1.1: Hydrogenation / 2.1: Deacetylation / 3.1: Tosylation / 4.1: Mitsunobu reaction / 5.1: Hydrolysis / 6.1: Etherification / 7.1: Alkylation / 8.1: ozonolysis / 8.2: Decomposition / 9.1: deprotonation / 9.2: Wittig reaction / 10.1: Epoxidation;
DOI:10.1016/S0040-4020(00)00878-4
