(-)-tert-Butyl (S)-2-hydroxybutyrate

Base Information

Chemical Name:(-)-tert-Butyl (S)-2-hydroxybutyrate
CAS No.:37787-90-9
Molecular Formula:C8H16 O3
Molecular Weight:160.213
Hs Code.:2918199090
DSSTox Substance ID:DTXSID80530956
Wikidata:Q82402446
Mol file:37787-90-9.mol

Synonyms:37787-90-9;(-)-tert-Butyl (S)-2-hydroxybutyrate;tert-Butyl (2S)-2-hydroxybutanoate;tert-Butyl(S)-(-)-2-hydroxybutyrate;TERT-BUTYL (S)-(-)-2-HYDROXYBUTYRATE;tert-butyl (s)-2-hydroxybutyrate;ISOAMYLPYRUVATE;tert-Butyl-(S)-(-)-2-hydroxybutyrate;SCHEMBL1485462;Tert-butyl(S)-2-hydroxybutyrate;DTXSID80530956;UPRLOYNUXQZAPJ-LURJTMIESA-N;(S)-tert-butyl 2-hydroxybutanoate;MFCD00210054;tert-butyl (S)-(-)-hydroxybutyrate;AKOS025295247;tert-Butyl (2S)-(-)-2-hydroxybutanoate;(S)-2-hydroxy-butyric acid tert-butyl ester;(-)-tert-Butyl (S)-2-hydroxybutyrate, 98%;P17852;(-)-tert-Butyl (S)-2-hydroxybutyrate, >=97.0% (sum of enantiomers, GC)

Suppliers and Price of (-)-tert-Butyl (S)-2-hydroxybutyrate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
(?)-tert-Butyl (S)-2-hydroxybutyrate ≥97.0% (sum of enantiomers, GC)
250mg-f
$ 256.00

American Custom Chemicals Corporation
(-)-TERT-BUTYL (S)-2-HYDROXYBUTYRATE 95.00%
250MG
$ 822.24

Total 10 raw suppliers

Chemical Property of (-)-tert-Butyl (S)-2-hydroxybutyrate

Chemical Property:

Vapor Pressure:0.286mmHg at 25°C
Melting Point:50-54 ºC(lit.)
Boiling Point:179.1 ºCat 760 mmHg
Flash Point:58.8 ºC
PSA：46.53000
Density:0.988 g/cm³
LogP:1.09900
Storage Temp.:2-8°C
XLogP3:1.4
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:160.109944368
Heavy Atom Count:11
Complexity:135

Purity/Quality:

98%,99%, ^*data from raw suppliers

(?)-tert-Butyl (S)-2-hydroxybutyrate ≥97.0% (sum of enantiomers, GC) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: 22-24/25

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCC(C(=O)OC(C)(C)C)O
Isomeric SMILES:CC[C@@H](C(=O)OC(C)(C)C)O

Technology Process of (-)-tert-Butyl (S)-2-hydroxybutyrate

There total 2 articles about (-)-tert-Butyl (S)-2-hydroxybutyrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: (S)-tert-butyl 2-acetoxybutanoate

: 37787-90-9
(S)-tert-butyl 2-hydroxybutanoate

Guidance literature:: With potassium carbonate; In methanol; water; at 20 ℃;
DOI:10.1016/j.bmcl.2017.09.006

Reference yield:

: 37472-51-8
tert-butyl 2-oxybutanoate

: 206996-51-2
(R)-2-hydroxy-butyric acid tert-butyl ester

: 37787-90-9
(S)-tert-butyl 2-hydroxybutanoate

Guidance literature:: With 3-pinanyl-9-borabicyclo[3.3.1]nonane; at 0 ℃; for 24h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1021/jo00209a008