4-Propylbiphenyl

Base Information

• Chemical Name: 4-Propylbiphenyl
• CAS No.: 10289-45-9
• Molecular Formula: C15H16
• Molecular Weight: 196.292
• Hs Code.: 29029090
• DSSTox Substance ID: DTXSID10908109
• Nikkaji Number: J1.630.667C
• Wikidata: Q72502647
• Mol file: 10289-45-9.mol

Synonyms:4-Propylbiphenyl;4-Propyl-1,1'-biphenyl;10289-45-9;4-n-Propylbiphenyl;71294-42-3;1-phenyl-4-propylbenzene;1,1'-biphenyl, 4-propyl-;4-Propyl-1,1'-diphenyl;MFCD00102114;1-phenyl-4-propyl-benzene;?4-Propylbiphenyl;4-n-propyl biphenyl;Biphenyl, 4-propyl-;DTXSID10908109;NAYIXKXYHOLMRC-UHFFFAOYSA-N;BCP11770;AKOS015888897;SB66350;DS-15324;SY048771;CS-0152416;FT-0641343;P1216;F16559;A837147;A896683

Chemical Property of 4-Propylbiphenyl

Chemical Property:

• Appearance/Colour: Clear pale yellow liquid or low melting solid
• Vapor Pressure: 0.00158mmHg at 25°C
• Melting Point: 5-17 °C
• Refractive Index: 1.55
• Boiling Point: 304.4 °C at 760 mmHg
• Flash Point: 141.4 °C
• PSA: 0.00000
• Density: 0.962 g/cm³
• LogP: 4.30610
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 5.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 196.125200510
• Heavy Atom Count: 15
• Complexity: 159

Purity/Quality:

4-Propylbiphenyl ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC1=CC=C(C=C1)C2=CC=CC=C2

Technology Process of 4-Propylbiphenyl

There total 29 articles about 4-Propylbiphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

1-biphenyl-4-yl-propan-1-one (37940-57-1) → 4-propyl-1,1'-biphenyl (10289-45-9)

Guidance literature:

With iron(III) chloride; hydrogen; titanium(IV) oxide; platinum; In isopropyl alcohol; at 80 ℃; for 2h; under 7500.75 Torr; Autoclave;

Reference yield: 85.0%

p-phenylcyclohexylidenecyclopropane (147356-80-7) → 4-propyl-1,1'-biphenyl (10289-45-9)

Guidance literature:

With (triphenylphosphine)gold(I) chloride; silver trifluoromethanesulfonate; In toluene; at 100 ℃; for 10h; Inert atmosphere;

DOI:10.1021/ol902593f

Reference yield: 83.0%

C22H22N2O2S → 4-propyl-1,1'-biphenyl (10289-45-9)

Guidance literature:

With dichloro bis(1,4-diazabicyclo[2.2.2]octane)(BH₄)Zr(IV); toluene-4-sulfonic acid; In sulfolane; N,N-dimethyl-formamide; at 110 ℃; for 12.1h;

DOI:10.1055/s-2004-836038

upstream raw materials:

propan-1-ol

biphenyl

1-biphenyl-4-yl-propan-1-one

isopropyl alcohol

Downstream raw materials:

1-(4'-propyl-[1,1'-biphenyl]-4-yl)ethanone

4-n-propyl-4'-bromobiphenyl

4-ethenyl-4'-propyl-1,1'-biphenyl

1-(4-biphenylyl)-2-propanone

Refernces

• 1、 Repkin,Nesterova,Nesterov,Golovin. "Thermal transformations of 4-tert-butylbiphenyl". . p. 149 - 153. Retrieved 2010.
• 2、 -. "Synthesis method of 4-alkyl biphenylacetylene". Paragraph 0045-0046. . Retrieved 2021/06/13.
• 3、 Aschenaki, Assefa,Bao, James Jianmin,Jia, Wenhui,Li, Youxin,Liu, Jia,Ren, Fangfang,Song, Qianyi,Zheng, Wenqing. "Preparation of a magnetic and recyclable superparamagnetic silica support with a boronic acid group for immobilizing Pd catalysts and its applications in Suzuki reactions". . p. 33692 - 33702. Retrieved 2021/12/07.