Technology Process of (hydroxymethyl)methylphenylgermane
There total 1 articles about (hydroxymethyl)methylphenylgermane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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In
diethyl ether;
to a suspn. of LiAlH4 in diethyl ether is added a soln. of Ge-compd. in diethyl ether with stirring and ice-cooling, the mixt. is stirred for 3 h under reflux, addn. of aq. HCl at 0°C (N2); the aq. phase is sepd., extd. with diethyl ether (three times), combined etheral extracts are dried (Al2O3), the solvent is distd. off under normal pressure, residue is distd. (Vigreux-column), elem. anal.;
- Guidance literature:
-
With
acetic anhydride; triethylamine;
In
diethyl ether; pentane;
to a soln. of Ge-compd. and triethyl amine in pentane is added a soln. of acetic acid anhydride in diethyl ether, mixt. is stirred at 60°C for 6 h (N2).; react. mixt. is extd. with water (four times), the organic phase is dried over Na2SO4 and the solvent is evapd. under reduced pressure, residue is distd. in vac. at 60°C/0.01 Torr, elem. anal.;
