Technology Process of acetoxy(acetoxymethyl)methylphenylgermane
There total 1 articles about acetoxy(acetoxymethyl)methylphenylgermane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
acetic acid; triethylamine;
In
toluene;
to a soln. containing triethyl amine and a mixt. of the Ge-compds. in toluene is added dropwise glacial acetic acid, mixt. is stirred for 6 h under reflux (N2); ppt. is filtd. off, washed with petroleum ether, filtrate is evapd. to dryness, residue is distd. in vac. (Vigreux column), elem. anal.;
- Guidance literature:
-
In
diethyl ether;
to a suspn. of LiAlH4 in diethyl ether is added a soln. of Ge-compd. in diethyl ether with stirring and ice-cooling, the mixt. is stirred for 3 h under reflux, addn. of aq. HCl at 0°C (N2); the aq. phase is sepd., extd. with diethyl ether (three times), combined etheral extracts are dried (Al2O3), the solvent is distd. off under normal pressure, residue is distd. (Vigreux-column), elem. anal.;
