1-(tert-Butyl-dimethyl-silanyloxy)-2-[(E)-6-(tert-butyl-diphenyl-silanyloxy)-4-methyl-hex-4-enyl]-benzene

Base Information

Chemical Name:1-(tert-Butyl-dimethyl-silanyloxy)-2-[(E)-6-(tert-butyl-diphenyl-silanyloxy)-4-methyl-hex-4-enyl]-benzene
CAS No.:151951-00-7
Molecular Formula:C₃₅H₅₀O₂Si₂
Molecular Weight:558.952
Hs Code.:

Synonyms:1-(tert-Butyl-dimethyl-silanyloxy)-2-[(E)-6-(tert-butyl-diphenyl-silanyloxy)-4-methyl-hex-4-enyl]-benzene

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Chemical Property of 1-(tert-Butyl-dimethyl-silanyloxy)-2-[(E)-6-(tert-butyl-diphenyl-silanyloxy)-4-methyl-hex-4-enyl]-benzene

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Technology Process of 1-(tert-Butyl-dimethyl-silanyloxy)-2-[(E)-6-(tert-butyl-diphenyl-silanyloxy)-4-methyl-hex-4-enyl]-benzene

There total 8 articles about 1-(tert-Butyl-dimethyl-silanyloxy)-2-[(E)-6-(tert-butyl-diphenyl-silanyloxy)-4-methyl-hex-4-enyl]-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 151950-96-8
(E)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-phenyl]-3-methyl-hex-2-en-1-ol

: 151951-00-7
1-(tert-Butyl-dimethyl-silanyloxy)-2-[(E)-6-(tert-butyl-diphenyl-silanyloxy)-4-methyl-hex-4-enyl]-benzene

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 23 ℃;
DOI:10.1021/ja00071a079

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 151951-00-7
1-(tert-Butyl-dimethyl-silanyloxy)-2-[(E)-6-(tert-butyl-diphenyl-silanyloxy)-4-methyl-hex-4-enyl]-benzene

Guidance literature:: Multi-step reaction with 7 steps

1: 100 percent / Et₃N / CH₂Cl₂ / 23 °C

2: OsO₄, NaIO₄, H₂O / tetrahydrofuran / 23 °C

3: benzene / 50 °C

4: H₂ / Pd/C / ethanol / 23 °C

5: NaH / tetrahydrofuran / 23 °C

6: Dibal-H / diethyl ether / -78 °C

7: 91 percent / Et₃N, 4-dimethylaminopyridine / CH₂Cl₂ / 23 °C

With dmap; sodium periodate; osmium(VIII) oxide; water; hydrogen; sodium hydride; diisobutylaluminium hydride; triethylamine; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; benzene;
DOI:10.1021/ja00071a079

Reference yield:

: 151950-94-6
1-tert-butyldimethylsilyloxy-2-(2-propenyl)benzene

: 151951-00-7
1-(tert-Butyl-dimethyl-silanyloxy)-2-[(E)-6-(tert-butyl-diphenyl-silanyloxy)-4-methyl-hex-4-enyl]-benzene

Guidance literature:: Multi-step reaction with 6 steps

1: OsO₄, NaIO₄, H₂O / tetrahydrofuran / 23 °C

2: benzene / 50 °C

3: H₂ / Pd/C / ethanol / 23 °C

4: NaH / tetrahydrofuran / 23 °C

5: Dibal-H / diethyl ether / -78 °C

6: 91 percent / Et₃N, 4-dimethylaminopyridine / CH₂Cl₂ / 23 °C

With dmap; sodium periodate; osmium(VIII) oxide; water; hydrogen; sodium hydride; diisobutylaluminium hydride; triethylamine; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; benzene;
DOI:10.1021/ja00071a079