1-(diethyltriazenyl)-3-(3'-ethylheptyl)-4-<(trimethylsilyl)ethynyl>benzene

Base Information

Chemical Name:1-(diethyltriazenyl)-3-(3'-ethylheptyl)-4-<(trimethylsilyl)ethynyl>benzene
CAS No.:174753-18-5
Molecular Formula:C₂₄H₄₁N₃Si
Molecular Weight:399.695
Hs Code.:

Synonyms:1-(diethyltriazenyl)-3-(3'-ethylheptyl)-4-<(trimethylsilyl)ethynyl>benzene

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Chemical Property of 1-(diethyltriazenyl)-3-(3'-ethylheptyl)-4-<(trimethylsilyl)ethynyl>benzene

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Technology Process of 1-(diethyltriazenyl)-3-(3'-ethylheptyl)-4-<(trimethylsilyl)ethynyl>benzene

There total 14 articles about 1-(diethyltriazenyl)-3-(3'-ethylheptyl)-4-<(trimethylsilyl)ethynyl>benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 187867-57-8
1-(3'-nitrophenyl)-3-ethylheptane-1-one

: 174753-18-5
1-(diethyltriazenyl)-3-(3'-ethylheptyl)-4-<(trimethylsilyl)ethynyl>benzene

Guidance literature:: Multi-step reaction with 8 steps

1: 67 percent / NaBH₄ / ethanol / 1 h / 0 °C

2: 97 percent / 4-(N,N-dimethylamino)pyridine / pyridine / 0.17 h / 0 °C

3: 60 percent / liq. NH₃, Li / tetrahydrofuran / 1.) -78 deg C, 30 min, 2.) -33 deg C, 1 h

4: 87 percent / 1 N NaOH / tetrahydrofuran / 2 h / Heating

5: AlCl₃ / CS₂ / 3 h / 70 °C

6: 3 N NaOH

7: 1.) t-BuONO, BF₃-OEt₂, 2.) K₂CO₃ / 1.) CH₂Cl₂, 0 deg C, 30 min, 2.) 1 h

With dmap; sodium hydroxide; sodium tetrahydroborate; aluminium trichloride; tert.-butylnitrite; boron trifluoride diethyl etherate; ammonia; lithium; potassium carbonate; In tetrahydrofuran; pyridine; carbon disulfide; ethanol;
DOI:10.1021/jo962336q

Reference yield:

: 187871-08-5
1-(3'-nitrophenyl)-3-ethylheptane-1-ol

: 174753-18-5
1-(diethyltriazenyl)-3-(3'-ethylheptyl)-4-<(trimethylsilyl)ethynyl>benzene

Guidance literature:: Multi-step reaction with 7 steps

1: 97 percent / 4-(N,N-dimethylamino)pyridine / pyridine / 0.17 h / 0 °C

2: 60 percent / liq. NH₃, Li / tetrahydrofuran / 1.) -78 deg C, 30 min, 2.) -33 deg C, 1 h

3: 87 percent / 1 N NaOH / tetrahydrofuran / 2 h / Heating

4: AlCl₃ / CS₂ / 3 h / 70 °C

5: 3 N NaOH

6: 1.) t-BuONO, BF₃-OEt₂, 2.) K₂CO₃ / 1.) CH₂Cl₂, 0 deg C, 30 min, 2.) 1 h

With dmap; sodium hydroxide; aluminium trichloride; tert.-butylnitrite; boron trifluoride diethyl etherate; ammonia; lithium; potassium carbonate; In tetrahydrofuran; pyridine; carbon disulfide;
DOI:10.1021/jo962336q

Reference yield:

: 187871-13-2
1-(3'-nitrophenyl)-1-acetoxy-3-ethylheptane

: 174753-18-5
1-(diethyltriazenyl)-3-(3'-ethylheptyl)-4-<(trimethylsilyl)ethynyl>benzene

Guidance literature:: Multi-step reaction with 6 steps

1: 60 percent / liq. NH₃, Li / tetrahydrofuran / 1.) -78 deg C, 30 min, 2.) -33 deg C, 1 h

2: 87 percent / 1 N NaOH / tetrahydrofuran / 2 h / Heating

3: AlCl₃ / CS₂ / 3 h / 70 °C

4: 3 N NaOH

5: 1.) t-BuONO, BF₃-OEt₂, 2.) K₂CO₃ / 1.) CH₂Cl₂, 0 deg C, 30 min, 2.) 1 h

With sodium hydroxide; aluminium trichloride; tert.-butylnitrite; boron trifluoride diethyl etherate; ammonia; lithium; potassium carbonate; In tetrahydrofuran; carbon disulfide;
DOI:10.1021/jo962336q