(S)-1-methylheptyl 3-(4'-dodecyloxybiphenyl-4-ylcarbonyloxy)biphenyl-4'-carboxylate

Base Information

Chemical Name:(S)-1-methylheptyl 3-(4'-dodecyloxybiphenyl-4-ylcarbonyloxy)biphenyl-4'-carboxylate
CAS No.:1225650-92-9
Molecular Formula:C₄₆H₅₈O₅
Molecular Weight:690.964
Hs Code.:

Synonyms:(S)-1-methylheptyl 3-(4'-dodecyloxybiphenyl-4-ylcarbonyloxy)biphenyl-4'-carboxylate

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Chemical Property of (S)-1-methylheptyl 3-(4'-dodecyloxybiphenyl-4-ylcarbonyloxy)biphenyl-4'-carboxylate

Chemical Property:

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Technology Process of (S)-1-methylheptyl 3-(4'-dodecyloxybiphenyl-4-ylcarbonyloxy)biphenyl-4'-carboxylate

There total 8 articles about (S)-1-methylheptyl 3-(4'-dodecyloxybiphenyl-4-ylcarbonyloxy)biphenyl-4'-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 53676-04-3
4'-(dodecyloxy)biphenyl-4-carboxylic acid

: 1225651-70-6
(S)-1-methylheptyl 3-hydroxybiphenyl-4'-carboxylate

: 1225650-92-9
(S)-1-methylheptyl 3-(4'-dodecyloxybiphenyl-4-ylcarbonyloxy)biphenyl-4'-carboxylate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃;
DOI:10.1039/b923267b

Reference yield:

: 53087-13-1
3-(benzyloxy)phenyl bromide

: 1225650-92-9
(S)-1-methylheptyl 3-(4'-dodecyloxybiphenyl-4-ylcarbonyloxy)biphenyl-4'-carboxylate

Guidance literature:: Multi-step reaction with 4 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere

1.2: -78 - 20 °C / Inert atmosphere

1.3: Inert atmosphere

2.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / 1,2-dimethoxyethane; water / Inert atmosphere; Reflux

3.1: palladium 10% on activated carbon; hydrogen / ethyl acetate / 16 h / 1810.07 Torr

4.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 20 °C

With dmap; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; palladium 10% on activated carbon; hydrogen; sodium carbonate; dicyclohexyl-carbodiimide; In tetrahydrofuran; 1,2-dimethoxyethane; hexane; dichloromethane; water; ethyl acetate; 2.1: Suzuki coupling;
DOI:10.1039/b923267b

Reference yield:

: 1160843-08-2
(S)-1-methylheptyl 4-bromobenzoate

: 1225650-92-9
(S)-1-methylheptyl 3-(4'-dodecyloxybiphenyl-4-ylcarbonyloxy)biphenyl-4'-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / 1,2-dimethoxyethane; water / Inert atmosphere; Reflux

2: palladium 10% on activated carbon; hydrogen / ethyl acetate / 16 h / 1810.07 Torr

3: dmap; dicyclohexyl-carbodiimide / dichloromethane / 20 °C

With dmap; tetrakis(triphenylphosphine) palladium⁽⁰⁾; palladium 10% on activated carbon; hydrogen; sodium carbonate; dicyclohexyl-carbodiimide; In 1,2-dimethoxyethane; dichloromethane; water; ethyl acetate; 1: Suzuki coupling;
DOI:10.1039/b923267b