Methyl 3-(2-thienyl)benzoate

Base Information

Chemical Name:Methyl 3-(2-thienyl)benzoate
CAS No.:17595-85-6
Molecular Formula:C₁₂H₁₀O₂S
Molecular Weight:218.276
Hs Code.:
DSSTox Substance ID:DTXSID70399635
Nikkaji Number:J1.994.414J
Wikidata:Q82202299

Synonyms:17595-85-6;methyl 3-(2-thienyl)benzoate;3-thiophen-2-ylbenzoic acid methyl ester;2-(3-methoxycarbonylphenyl)thiophene;SCHEMBL6802813;DTXSID70399635;MTYCPVXBEPSDOY-UHFFFAOYSA-N;methyl 3-(thiophen-2-yl)benzoate;MFCD06204245;AKOS004113975;3-(2-Thienyl)benzoic acid methyl ester;BB 0222676

Suppliers and Price of Methyl 3-(2-thienyl)benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of Methyl 3-(2-thienyl)benzoate

Chemical Property:

XLogP3:3.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:218.04015073
Heavy Atom Count:15
Complexity:230

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=CC=CC(=C1)C2=CC=CS2

Technology Process of Methyl 3-(2-thienyl)benzoate

There total 6 articles about Methyl 3-(2-thienyl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 618-89-3
methyl 3-bromobenzoate

: 15106-95-3
bis(thien-2-yl)zinc

: 17595-85-6
methyl 3-(thiophen-2-yl)benzoate

Guidance literature:: With catalyst 1 (aliphatic, phosphine based pincer complex of palladium); In 1,4-dioxane; 1-methyl-pyrrolidin-2-one; at 100 ℃; for 1h;
DOI:10.1039/C1DT90189C

Reference yield: 80.0%

: 1003-09-4
2-bromothiophene

: 99769-19-4
[3-(methoxycarbonyl)phenyl]boronic acid

: 17595-85-6
methyl 3-(thiophen-2-yl)benzoate

Guidance literature:: With sodium carbonate; In ethanol; water; at 60 ℃; for 12h; Catalytic behavior;
DOI:10.1016/j.jorganchem.2018.02.030

Reference yield:

: 3-[2-(m-iodobenzoyloxy)ethyl]-1-methylimidazolium tetrafluoroborate

: 17595-85-6
methyl 3-(thiophen-2-yl)benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: CsF; Pd(OAc)2 / H₂O / 22 h / 80 °C

2: ammonia / 20 °C

With palladium diacetate; ammonia; cesium fluoride; In water; 1: Suzuki reaction;
DOI:10.1021/ol035977y