tert-butyl (3S,4S,5R,αS)-3-[N-benzyl-N-(α-methylbenzyl)amino]-4,5-O-isopropylidene-hepta-6-enoate

Base Information

Chemical Name:tert-butyl (3S,4S,5R,αS)-3-[N-benzyl-N-(α-methylbenzyl)amino]-4,5-O-isopropylidene-hepta-6-enoate
CAS No.:1169755-24-1
Molecular Formula:C₂₉H₃₉NO₄
Molecular Weight:465.633
Hs Code.:

Synonyms:tert-butyl (3S,4S,5R,αS)-3-[N-benzyl-N-(α-methylbenzyl)amino]-4,5-O-isopropylidene-hepta-6-enoate

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Chemical Property of tert-butyl (3S,4S,5R,αS)-3-[N-benzyl-N-(α-methylbenzyl)amino]-4,5-O-isopropylidene-hepta-6-enoate

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Technology Process of tert-butyl (3S,4S,5R,αS)-3-[N-benzyl-N-(α-methylbenzyl)amino]-4,5-O-isopropylidene-hepta-6-enoate

There total 2 articles about tert-butyl (3S,4S,5R,αS)-3-[N-benzyl-N-(α-methylbenzyl)amino]-4,5-O-isopropylidene-hepta-6-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

: 17480-69-2
(S)-N-benzyl-1-phenylethylamine

: 1085845-83-5
tert-butyl (2E,4S,5R)-4,5-O-isopropylidene-hepta-2,6-dienoate

: 1169755-24-1
tert-butyl (3S,4S,5R,αS)-3-[N-benzyl-N-(α-methylbenzyl)amino]-4,5-O-isopropylidene-hepta-6-enoate

: 1169755-25-2
tert-butyl (3R,4S,5R,αS)-3-[N-benzyl-N-(α-methylbenzyl)amino]-4,5-O-isopropylidene-hepta-6-enoate

Guidance literature:: (S)-N-benzyl-1-phenylethylamine; With n-butyllithium; In diethyl ether; hexane; at -20 ℃; Inert atmosphere;

tert-butyl (2E,4S,5R)-4,5-O-isopropylidene-hepta-2,6-dienoate; In diethyl ether; hexane; at -20 ℃; diastereoselective reaction; Inert atmosphere;
DOI:10.1039/b818298a

Reference yield:

: 17480-69-2
(S)-N-benzyl-1-phenylethylamine

: 102-97-6
Benzyl-isopropyl-amin

: 1085845-83-5
tert-butyl (2E,4S,5R)-4,5-O-isopropylidene-hepta-2,6-dienoate

: 1169755-24-1
tert-butyl (3S,4S,5R,αS)-3-[N-benzyl-N-(α-methylbenzyl)amino]-4,5-O-isopropylidene-hepta-6-enoate

: 1169755-25-2
tert-butyl (3R,4S,5R,αS)-3-[N-benzyl-N-(α-methylbenzyl)amino]-4,5-O-isopropylidene-hepta-6-enoate

: C₁₄H₂₂O₄

: 1137951-83-7
tert-butyl (3S,4S,5R)-3-(N-benzyl-N-isopropylamino)-4,5-O-isopropylidene-hepta-6-enoate

Guidance literature:: (S)-N-benzyl-1-phenylethylamine; Benzyl-isopropyl-amin; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; Inert atmosphere;

tert-butyl (2E,4S,5R)-4,5-O-isopropylidene-hepta-2,6-dienoate; In tetrahydrofuran; hexane; at -78 ℃; diastereoselective reaction; Inert atmosphere;
DOI:10.1039/b818298a

Reference yield: 9.0%

: 1169755-24-1
tert-butyl (3S,4S,5R,αS)-3-[N-benzyl-N-(α-methylbenzyl)amino]-4,5-O-isopropylidene-hepta-6-enoate

: 75-05-8,26809-02-9
acetonitrile

: 36065-27-7,6284-14-6
N-α-phenylethylacetamide

: 698394-46-6
(2R,3R,4S,5S)-N⁽¹⁾-benzyl-2-iodomethyl-3,4-O-isopropylidene-5-(tert-butoxycarbonylmethyl)pyrrolidine

: 698394-45-5
(2S,3R,4S,5S)-N⁽¹⁾-benzyl-2-iodomethyl-3,4-O-isopropylidene-5-(tert-butoxycarbonylmethyl)pyrrolidine

Guidance literature:: With iodine; sodium hydrogencarbonate; at -20 - 20 ℃; for 22h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1016/j.tetasy.2009.02.014