5-O-benzoyl-3-O-benzyl-6-deoxy-6-diethylphosphono-1,2-O-isopropylidene-α-D-glucofuranose

Base Information

Chemical Name:5-O-benzoyl-3-O-benzyl-6-deoxy-6-diethylphosphono-1,2-O-isopropylidene-α-D-glucofuranose
CAS No.:1601493-71-3
Molecular Formula:C₂₇H₃₅O₉P
Molecular Weight:534.543
Hs Code.:

Synonyms:5-O-benzoyl-3-O-benzyl-6-deoxy-6-diethylphosphono-1,2-O-isopropylidene-α-D-glucofuranose

Suppliers and Price of 5-O-benzoyl-3-O-benzyl-6-deoxy-6-diethylphosphono-1,2-O-isopropylidene-α-D-glucofuranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 5-O-benzoyl-3-O-benzyl-6-deoxy-6-diethylphosphono-1,2-O-isopropylidene-α-D-glucofuranose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 5-O-benzoyl-3-O-benzyl-6-deoxy-6-diethylphosphono-1,2-O-isopropylidene-α-D-glucofuranose

There total 7 articles about 5-O-benzoyl-3-O-benzyl-6-deoxy-6-diethylphosphono-1,2-O-isopropylidene-α-D-glucofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 3-O-benzyl-6-deoxy-6-diethylphosphono-1,2-O-isopropylidene-α-d-glucofuranose

: 98-88-4
benzoyl chloride

: 1601493-71-3
5-O-benzoyl-3-O-benzyl-6-deoxy-6-diethylphosphono-1,2-O-isopropylidene-α-D-glucofuranose

Guidance literature:: With pyridine; at 20 ℃; Inert atmosphere;
DOI:10.1016/j.ejmech.2014.02.055

Reference yield:

: 22529-61-9
(1R)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro(2,3-d)(1,3)dioxol-5-yl)ethane-1,2-diol

: 1601493-71-3
5-O-benzoyl-3-O-benzyl-6-deoxy-6-diethylphosphono-1,2-O-isopropylidene-α-D-glucofuranose

Guidance literature:: Multi-step reaction with 4 steps

1.1: dmap; pyridine / 0.25 h / 0 °C

1.2: 0 - 20 °C

2.1: sodium iodide / acetone / Inert atmosphere; Reflux

3.1: 48 h / 110 °C / Inert atmosphere

4.1: pyridine / 20 °C / Inert atmosphere

With pyridine; dmap; sodium iodide; In acetone; 3.1: |Michaelis-Arbuzov Synthesis;
DOI:10.1016/j.ejmech.2014.02.055

Reference yield:

: 18685-18-2
3-O-benzyl-1,2-5,6-O-diisopropylidene-α-D-glucofuranose

: 1601493-71-3
5-O-benzoyl-3-O-benzyl-6-deoxy-6-diethylphosphono-1,2-O-isopropylidene-α-D-glucofuranose

Guidance literature:: Multi-step reaction with 5 steps

1.1: acetic acid / water / 1 h / 60 °C

2.1: dmap; pyridine / 0.25 h / 0 °C

2.2: 0 - 20 °C

3.1: sodium iodide / acetone / Inert atmosphere; Reflux

4.1: 48 h / 110 °C / Inert atmosphere

5.1: pyridine / 20 °C / Inert atmosphere

With pyridine; dmap; acetic acid; sodium iodide; In water; acetone; 4.1: |Michaelis-Arbuzov Synthesis;
DOI:10.1016/j.ejmech.2014.02.055