3-[(tert-butyl-dimethyl-silanyloxy)-(4-pent-1-enyl-phenyl)-methyl]-benzaldehyde

Base Information

Chemical Name:3-[(tert-butyl-dimethyl-silanyloxy)-(4-pent-1-enyl-phenyl)-methyl]-benzaldehyde
CAS No.:164981-03-7
Molecular Formula:C₂₅H₃₄O₂Si
Molecular Weight:394.629
Hs Code.:

3-[(<i>tert</i>-butyl-dimethyl-silanyloxy)-(4-pent-1-enyl-phenyl)-methyl]-benzaldehyde

Synonyms:3-[(tert-butyl-dimethyl-silanyloxy)-(4-pent-1-enyl-phenyl)-methyl]-benzaldehyde

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Chemical Property of 3-[(tert-butyl-dimethyl-silanyloxy)-(4-pent-1-enyl-phenyl)-methyl]-benzaldehyde

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Technology Process of 3-[(tert-butyl-dimethyl-silanyloxy)-(4-pent-1-enyl-phenyl)-methyl]-benzaldehyde

There total 5 articles about 3-[(tert-butyl-dimethyl-silanyloxy)-(4-pent-1-enyl-phenyl)-methyl]-benzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 164981-02-6
tert-butyl-[(3-dimethoxymethyl-phenyl)-(4-pent-1-enyl-phenyl)-methoxy]-dimethyl-silane

: 164981-03-7
3-[(tert-butyl-dimethyl-silanyloxy)-(4-pent-1-enyl-phenyl)-methyl]-benzaldehyde

Guidance literature:: With sulfuric acid; silica gel; In dichloromethane; at 20 ℃; for 1.5h;
DOI:10.1016/S0040-4039(02)01056-0

Reference yield:

: 626-19-7
Isophthalaldehyde

: 164981-03-7
3-[(tert-butyl-dimethyl-silanyloxy)-(4-pent-1-enyl-phenyl)-methyl]-benzaldehyde

Guidance literature:: Multi-step reaction with 5 steps

1.1: 90 percent / NH₄NO₃ / methanol / 2 h / Heating

2.1: 88 percent / SiO₂; aq. H₂SO₄ / CH₂Cl₂ / 0.75 h / 20 °C

3.1: nBuLi / hexamethylphosphoric acid triamide; tetrahydrofuran / 1.5 h / -80 °C

3.2: secBuLi / tetrahydrofuran / -80 °C

4.1: 92 percent / imidazole / dimethylformamide / 15 h / 20 °C

5.1: 100 percent / SiO₂; aq. H₂SO₄ / CH₂Cl₂ / 1.5 h / 20 °C

With 1H-imidazole; ammonium nitrate; n-butyllithium; sulfuric acid; silica gel; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(02)01056-0

Reference yield:

: 37832-33-0
isophthalaldehyde bis-dimethylacetal

: 164981-03-7
3-[(tert-butyl-dimethyl-silanyloxy)-(4-pent-1-enyl-phenyl)-methyl]-benzaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1.1: 88 percent / SiO₂; aq. H₂SO₄ / CH₂Cl₂ / 0.75 h / 20 °C

2.1: nBuLi / hexamethylphosphoric acid triamide; tetrahydrofuran / 1.5 h / -80 °C

2.2: secBuLi / tetrahydrofuran / -80 °C

3.1: 92 percent / imidazole / dimethylformamide / 15 h / 20 °C

4.1: 100 percent / SiO₂; aq. H₂SO₄ / CH₂Cl₂ / 1.5 h / 20 °C

With 1H-imidazole; n-butyllithium; sulfuric acid; silica gel; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(02)01056-0