4-methoxycinnamyl ethyl carbonate

Base Information

• Chemical Name: 4-methoxycinnamyl ethyl carbonate
• CAS No.: 1181394-02-4
• Molecular Formula: C₁₃H₁₆O₄
• Molecular Weight: 236.268
• Mol file: 1181394-02-4.mol

Synonyms:4-methoxycinnamyl ethyl carbonate

Chemical Property of 4-methoxycinnamyl ethyl carbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-methoxycinnamyl ethyl carbonate

There total 1 articles about 4-methoxycinnamyl ethyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

p-methoxycinnamyl alcohol (53484-50-7,17581-85-0) + chloroformic acid ethyl ester (541-41-3) → 4-methoxycinnamyl ethyl carbonate (1181394-02-4)

Guidance literature:

With pyridine; In dichloromethane; Inert atmosphere;

DOI:10.1021/ja905059r

Reference yield: 70.0%

4-methoxycinnamyl ethyl carbonate (1181394-02-4) + ethyl cinnamylcarbonate (86537-61-3) → C19H21NO (1181394-32-0)

Guidance literature:

ethyl cinnamylcarbonate; With C₄₆H₄₅IrNO₂P; ammonia; In tetrahydrofuran; at 30 ℃; for 0.333333h; Inert atmosphere;

4-methoxycinnamyl ethyl carbonate; In tetrahydrofuran; at 20 ℃; optical yield given as %ee; enantioselective reaction; Inert atmosphere;

DOI:10.1021/ja905059r

Reference yield: 58.0%

4-methoxycinnamyl ethyl carbonate (1181394-02-4) → (R)-1-(4-methoxyphenyl)prop-2-en-1-amine hydrochloride (1181394-20-6)

Guidance literature:

4-methoxycinnamyl ethyl carbonate; With C₄₆H₄₅IrNO₂P; ammonia; In tetrahydrofuran; at 30 ℃; for 14h; Cooling with liquid nitrogen; Inert atmosphere;

With hydrogenchloride; In diethyl ether; dichloromethane; optical yield given as %ee; enantioselective reaction; Inert atmosphere;

DOI:10.1021/ja905059r

upstream raw materials:

p-methoxycinnamyl alcohol

chloroformic acid ethyl ester

Downstream raw materials:

(R)-1-(4-methoxyphenyl)prop-2-en-1-amine hydrochloride

C₁₉H₂₁NO