Lithium,(2-ethylhexyl)-

Base Information

• Chemical Name: Lithium,(2-ethylhexyl)-
• CAS No.: 13067-81-7
• Molecular Formula: C8H17 Li
• Molecular Weight: 120.164
• Hs Code.: 2931900090
• European Community (EC) Number: 658-075-6
• DSSTox Substance ID: DTXSID50450713
• Mol file: 13067-81-7.mol

Synonyms:Lithium,(2-ethylhexyl)-;13067-81-7;lithium;3-methanidylheptane;2-ethylhexyllithium;(2-ETHYLHEXYL)LITHIUM;DTXSID50450713;AKOS015910887;FT-0691667

Chemical Property of Lithium,(2-ethylhexyl)-

Chemical Property:

• Flash Point: -4℃
• PSA: 0.00000
• Density: 0.730g/mLat25℃
• LogP: 3.17040
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 120.14902898
• Heavy Atom Count: 9
• Complexity: 43.8

Purity/Quality:

99% ^*data from raw suppliers

2-ETHYLHEXYLLITHIUM 98.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,C,N
• Statements: 11-14-17-34-50/53-65-67-15
• Safety Statements: 16-26-29-33-36/37/39-43-45-60-61-62

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Li+].CCCCC([CH2-])CC

Technology Process of Lithium,(2-ethylhexyl)-

There total 1 articles about Lithium,(2-ethylhexyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

3-(chloromethyl)heptane (123-04-6) → (2-ethylhexyl)lithium (13067-81-7)

Guidance literature:

With lithium; In n-heptane; at 20 ℃;

DOI:10.1007/BF01431309

Reference yield: 81.0%

(E/Z)-1-benzyl 8-methyl oct-2-enedioate + (2-ethylhexyl)lithium (13067-81-7) → 1-benzyl 8-methyl 3-(2-ethylhexyl)octanedioate (1411986-14-5)

Guidance literature:

(2-ethylhexyl)lithium; With copper(I) bromide dimethylsulfide complex; In tetrahydrofuran; n-heptane; at -15 ℃; for 0.333333h;

(E/Z)-1-benzyl 8-methyl oct-2-enedioate; With chloro-trimethyl-silane; In tetrahydrofuran; n-heptane; at -78 ℃; for 3h;

DOI:10.1016/j.bmcl.2012.09.093

Reference yield: 21.0%

4,8-dihydrobenzo[1,2-b:4,5-b']dithiophene-4,8-dione (32281-36-0) + (2-ethylhexyl)lithium (13067-81-7) → 4,8-bis(2-ethylhexyl)benzo[1,2-b:4,5-b']dithiophene (1234306-29-6)

Guidance literature:

4,8-dihydrobenzo[1,2-b:4,5-b']dithiophene-4,8-dione; (2-ethylhexyl)lithium; In tetrahydrofuran; at 20 ℃; for 1.16667h; Inert atmosphere;

With hydrogenchloride; tin(ll) chloride; In tetrahydrofuran; water; for 3h; Reflux;

DOI:10.3987/COM-11-12390

upstream raw materials:

3-(chloromethyl)heptane

Downstream raw materials:

octane

3-methylheptane

5,8-diethyldodecane

benzyl potassium