μ-η2-(3-phenyl-2-propynal)dicobalthexacarbonyl

Base Information

Chemical Name:μ-η2-(3-phenyl-2-propynal)dicobalthexacarbonyl
CAS No.:90108-98-8
Molecular Formula:C₁₅H₆Co₂O₇
Molecular Weight:416.195
Hs Code.:

Synonyms:μ-η2-(3-phenyl-2-propynal)dicobalthexacarbonyl

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of μ-η2-(3-phenyl-2-propynal)dicobalthexacarbonyl

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Technology Process of μ-η2-(3-phenyl-2-propynal)dicobalthexacarbonyl

There total 4 articles about μ-η2-(3-phenyl-2-propynal)dicobalthexacarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 2579-22-8
Phenylpropargyl aldehyde

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 90108-98-8
μ-η2-(3-phenyl-2-propynal)dicobalthexacarbonyl

Guidance literature:: In dichloromethane; ligand in CH2Cl2 added at 0°C under N2 to a soln. of Co complex, stirred for 4 h; concd. (vac.), flash-chromd. (pentane/Et2O);
DOI:10.1021/om050019g

Reference yield: 27.0%

: 1515868-29-7
μ-η2-(3,3-diisopropoxy-1-phenyl-1-propyne)-dicobalthexacarbonyl

: dl-μ-η2-(3,4-diisopropoxy-1,6-diphenyl-1,5-hexadiyne)bis(dicobalthexacarbonyl)

: 1515868-52-6
μ-η2-(3-isopropoxy-1-phenyl-1-propyne)dicobalthexacarbonyl

: 90108-98-8
μ-η2-(3-phenyl-2-propynal)dicobalthexacarbonyl

Guidance literature:: μ-η2-(3,3-diisopropoxy-1-phenyl-1-propyne)-dicobalthexacarbonyl; With trifluoromethylsulfonic anhydride; In dichloromethane; at -50 - -10 ℃; for 0.5h; Inert atmosphere; Schlenk technique;

With cobaltocene; In dichloromethane; at -50 ℃; for 2.5h; diastereoselective reaction; Inert atmosphere; Schlenk technique;
DOI:10.1021/om400718w

Reference yield: 21.9%

: 1515868-45-7
μ-η2-(3-phenyl-2-propynal propylene glycol acetal)dicobalthexacarbonyl

: 90108-98-8
μ-η2-(3-phenyl-2-propynal)dicobalthexacarbonyl

Guidance literature:: μ-η2-(3-phenyl-2-propynal propylene glycol acetal)dicobalthexacarbonyl; With trifluoromethylsulfonic anhydride; In dichloromethane; at -20 ℃; for 0.25h; Inert atmosphere; Schlenk technique;

With zinc; In dichloromethane; at -20 - 20 ℃; for 2.25h; Inert atmosphere; Schlenk technique;
DOI:10.1021/om400718w