methyl (2Z,4S,5S,6E,8S,9R,10S,12S,13R)-5-<(t-butyldimethylsilyl)oxy>-13-<2,5-dimethoxy-3-<(triphenylmethyl)amino>phenyl>-4,9,10,13-tetramethoxy-6,8,12-trimethyl-2,6-tridecadienoate

Base Information

Chemical Name:methyl (2Z,4S,5S,6E,8S,9R,10S,12S,13R)-5-<(t-butyldimethylsilyl)oxy>-13-<2,5-dimethoxy-3-<(triphenylmethyl)amino>phenyl>-4,9,10,13-tetramethoxy-6,8,12-trimethyl-2,6-tridecadienoate
CAS No.:145798-88-5
Molecular Formula:C₅₄H₇₅NO₉Si
Molecular Weight:910.276
Hs Code.:

methyl (2Z,4S,5S,6E,8S,9R,10S,12S,13R)-5-<(t-butyldimethylsilyl)oxy>-13-<2,5-dimethoxy-3-<(triphenylmethyl)amino>phenyl>-4,9,10,13-tetramethoxy-6,8,12-trimethyl-2,6-tridecadienoate

Synonyms:methyl (2Z,4S,5S,6E,8S,9R,10S,12S,13R)-5-<(t-butyldimethylsilyl)oxy>-13-<2,5-dimethoxy-3-<(triphenylmethyl)amino>phenyl>-4,9,10,13-tetramethoxy-6,8,12-trimethyl-2,6-tridecadienoate

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Chemical Property of methyl (2Z,4S,5S,6E,8S,9R,10S,12S,13R)-5-<(t-butyldimethylsilyl)oxy>-13-<2,5-dimethoxy-3-<(triphenylmethyl)amino>phenyl>-4,9,10,13-tetramethoxy-6,8,12-trimethyl-2,6-tridecadienoate

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Technology Process of methyl (2Z,4S,5S,6E,8S,9R,10S,12S,13R)-5-<(t-butyldimethylsilyl)oxy>-13-<2,5-dimethoxy-3-<(triphenylmethyl)amino>phenyl>-4,9,10,13-tetramethoxy-6,8,12-trimethyl-2,6-tridecadienoate

There total 16 articles about methyl (2Z,4S,5S,6E,8S,9R,10S,12S,13R)-5-<(t-butyldimethylsilyl)oxy>-13-<2,5-dimethoxy-3-<(triphenylmethyl)amino>phenyl>-4,9,10,13-tetramethoxy-6,8,12-trimethyl-2,6-tridecadienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 88738-78-7
bis-(2,2,2-trifluoroethyl)(methoxycarbonylmethyl)phosphonate

: 137788-18-2
(E)-(2R,3S,6S,7R,8S,10S,11R)-3-(tert-Butyl-dimethyl-silanyloxy)-11-[2,5-dimethoxy-3-(trityl-amino)-phenyl]-2,7,8,11-tetramethoxy-4,6,10-trimethyl-undec-4-enal

: 145798-88-5
methyl (2Z,4S,5S,6E,8S,9R,10S,12S,13R)-5-<(t-butyldimethylsilyl)oxy>-13-<2,5-dimethoxy-3-<(triphenylmethyl)amino>phenyl>-4,9,10,13-tetramethoxy-6,8,12-trimethyl-2,6-tridecadienoate

Guidance literature:: With 18-crown-6 ether; potassium hexamethylsilazane; In tetrahydrofuran; at -78 ℃; for 4h;
DOI:10.1016/S0040-4039(00)79452-4

Reference yield:

: 115929-62-9
3-bromo-2,5-dimethoxyaniline

: 145798-88-5
methyl (2Z,4S,5S,6E,8S,9R,10S,12S,13R)-5-<(t-butyldimethylsilyl)oxy>-13-<2,5-dimethoxy-3-<(triphenylmethyl)amino>phenyl>-4,9,10,13-tetramethoxy-6,8,12-trimethyl-2,6-tridecadienoate

Guidance literature:: Multi-step reaction with 5 steps

1: 97 percent / NEt₃ / CH₂Cl₂ / 24 h / Ambient temperature

2: 1.) butyllithium / 1.) THF, hexane, -78 deg C, 0.5 h, 2.) THF, -78 deg C, 2 h

3: 100 percent / NaH / dimethylformamide / 6.5 h / 0 °C

4: 76 percent / OsO₄-NaIO₄, phosphate buffer / tetrahydrofuran / 16 h / Ambient temperature

5: 1.) 18-crown-6, potassium bis(trimethylsilyl)amide / 1.) THF, toluene, -78 deg C, 0.5 h, 2.) THF, toluene, -78 deg C, 1 h

With sodium periodate; osmium(VIII) oxide; n-butyllithium; phosphate buffer; 18-crown-6 ether; potassium hexamethylsilazane; sodium hydride; triethylamine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1246/bcsj.65.2974

Reference yield:

: 137788-08-0
(2S,4S,5R,6S,7E,9S,10S)-9-<(t-butyldimethylsilyl)oxy>-4,5,10-trimethoxy-2,6,8-trimethyl-7,11-dodecadienal

: 145798-88-5
methyl (2Z,4S,5S,6E,8S,9R,10S,12S,13R)-5-<(t-butyldimethylsilyl)oxy>-13-<2,5-dimethoxy-3-<(triphenylmethyl)amino>phenyl>-4,9,10,13-tetramethoxy-6,8,12-trimethyl-2,6-tridecadienoate

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) butyllithium / 1.) THF, hexane, -78 deg C, 0.5 h, 2.) THF, -78 deg C, 2 h

2: 100 percent / NaH / dimethylformamide / 6.5 h / 0 °C

3: 76 percent / OsO₄-NaIO₄, phosphate buffer / tetrahydrofuran / 16 h / Ambient temperature

4: 1.) 18-crown-6, potassium bis(trimethylsilyl)amide / 1.) THF, toluene, -78 deg C, 0.5 h, 2.) THF, toluene, -78 deg C, 1 h

With sodium periodate; osmium(VIII) oxide; n-butyllithium; phosphate buffer; 18-crown-6 ether; potassium hexamethylsilazane; sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1246/bcsj.65.2974