(1E,3Z)-1-(4-methanesulfonyl-2-nitrobuta-1,3-dien-1-yl)-4-methylbenzene

Base Information

Chemical Name:(1E,3Z)-1-(4-methanesulfonyl-2-nitrobuta-1,3-dien-1-yl)-4-methylbenzene
CAS No.:869624-51-1
Molecular Formula:C₁₂H₁₃NO₄S
Molecular Weight:267.306
Hs Code.:

Synonyms:(1E,3Z)-1-(4-methanesulfonyl-2-nitrobuta-1,3-dien-1-yl)-4-methylbenzene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1E,3Z)-1-(4-methanesulfonyl-2-nitrobuta-1,3-dien-1-yl)-4-methylbenzene

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Technology Process of (1E,3Z)-1-(4-methanesulfonyl-2-nitrobuta-1,3-dien-1-yl)-4-methylbenzene

There total 2 articles about (1E,3Z)-1-(4-methanesulfonyl-2-nitrobuta-1,3-dien-1-yl)-4-methylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: (1E,3Z)-1-methyl-4-(4-methylsulfanyl-2-nitrobuta-1,3-dien-1-yl)benzene

: 869624-51-1
(1E,3Z)-1-(4-methanesulfonyl-2-nitrobuta-1,3-dien-1-yl)-4-methylbenzene

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃;
DOI:10.1021/jo051059x

Reference yield:

: 4294-57-9
para-methylphenylmagnesium bromide

: 869624-51-1
(1E,3Z)-1-(4-methanesulfonyl-2-nitrobuta-1,3-dien-1-yl)-4-methylbenzene

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / tetrahydrofuran / 0 °C

2: 98 percent / m-chloroperoxybenzoic acid / CH₂Cl₂ / 20 °C

With 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo051059x

Reference yield: 100.0%

: 869624-51-1
(1E,3Z)-1-(4-methanesulfonyl-2-nitrobuta-1,3-dien-1-yl)-4-methylbenzene

: 33876-67-4
Phenyl <(4-methylphenyl)hydrazono>methyl ketone

: 1414846-51-7
3-benzoyl-6-(methylsulfonylmethyl)-5-nitro-1,4-di-p-tolyl-1,4,5,6-tetrahydropyridazine

Guidance literature:: Phenyl <(4-methylphenyl)hydrazono>methyl ketone; With potassium tert-butylate; In tetrahydrofuran; at 0 ℃; for 0.5h; Inert atmosphere;

(1E,3Z)-1-(4-methanesulfonyl-2-nitrobuta-1,3-dien-1-yl)-4-methylbenzene; In tetrahydrofuran; at 0 ℃;

With trifluoroacetic acid; In tetrahydrofuran; at 0 ℃; for 2h;
DOI:10.1016/j.tetlet.2012.09.040