1,2,3-triphenyl-3-formylcyclopropene

Base Information

• Chemical Name: 1,2,3-triphenyl-3-formylcyclopropene
• CAS No.: 79919-10-1
• Molecular Formula: C₂₂H₁₆O
• Molecular Weight: 296.368
• Mol file: 79919-10-1.mol

Synonyms:1,2,3-triphenyl-3-formylcyclopropene

Chemical Property of 1,2,3-triphenyl-3-formylcyclopropene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,2,3-triphenyl-3-formylcyclopropene

There total 2 articles about 1,2,3-triphenyl-3-formylcyclopropene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

1,2,3-triphenylcycloprop-2-ene-1-carbonitrile (79919-09-8) → 1,2,3-triphenyl-3-formylcyclopropene (79919-10-1)

Guidance literature:

With diisobutylaluminium hydride; In toluene; benzene; 1.) 5 deg C, 2.) from 5 deg C to room temperature, 2 h;

DOI:10.1021/jo00341a001

Reference yield:

1,2,3-triphenylcyclopropenylium perchlorate (51778-20-2,58003-32-0) → 1,2,3-triphenyl-3-formylcyclopropene (79919-10-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 18-crown-6

2: 68 percent / DIBAL / benzene; toluene / 2 h / 25 °C

With diisobutylaluminium hydride; 18-crown-6 ether; In toluene; benzene;

DOI:10.1016/S0040-4020(01)92374-9

Reference yield: 85.0%

1,2,3-triphenyl-3-formylcyclopropene (79919-10-1) → 1,2,3-triphenyl-3-(hydroxymethyl)cyclopropene (79919-12-3)

Guidance literature:

With sodium tetrahydroborate; at 0 ℃;

DOI:10.1016/S0040-4020(01)92374-9

upstream raw materials:

1,2,3-triphenylcycloprop-2-ene-1-carbonitrile

1,2,3-triphenylcyclopropenylium perchlorate

Downstream raw materials:

4-oxo-2,3,4-triphenyl-2-butenal

1,2,3-triphenyl-3-(hydroxymethyl)cyclopropene

Benzyl-[1-(1,2,3-triphenyl-cycloprop-2-enyl)-meth-(E)-ylidene]-amine

C₂₃H₂₀O