(TRIMETHYLSILYLMETHYL)TRIPHENYLPHOSPHONIUM IODIDE

Base Information

Chemical Name:(TRIMETHYLSILYLMETHYL)TRIPHENYLPHOSPHONIUM IODIDE
CAS No.:3739-98-8
Molecular Formula:C22H26 P Si . I
Molecular Weight:476.412
Hs Code.:2931900090
Mol file:3739-98-8.mol

Synonyms:Phosphonium,triphenyl[(trimethylsilyl)methyl]-, iodide (8CI,9CI);Triphenyl[(trimethylsilyl)methyl]phosphonium iodide (7CI);[(Trimethylsilyl)methyl]triphenylphosphonium iodide

Suppliers and Price of (TRIMETHYLSILYLMETHYL)TRIPHENYLPHOSPHONIUM IODIDE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
(TRIMETHYLSILYLMETHYL)TRIPHENYLPHOSPHONIUM IODIDE 95.00%
1G
$ 139.97

Alfa Aesar
(Trimethylsilylmethyl)triphenylphosphonium iodide 98%
5g
$ 88.60

Alfa Aesar
(Trimethylsilylmethyl)triphenylphosphonium iodide 98%
1g
$ 30.70

AHH
(Trimethylsilylmethyl)triphenylphosphonium iodide 98%
50g
$ 315.00

Total 14 raw suppliers

Chemical Property of (TRIMETHYLSILYLMETHYL)TRIPHENYLPHOSPHONIUM IODIDE

Chemical Property:

Melting Point:185 °C
Boiling Point:°Cat760mmHg
Flash Point:°C
PSA：13.59000
Density:g/cm³
LogP:2.28020
Sensitive.:Moisture & Light Sensitive

Purity/Quality:

98%min ^*data from raw suppliers

(TRIMETHYLSILYLMETHYL)TRIPHENYLPHOSPHONIUM IODIDE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s): R36/37/38:Irritating to eyes, respiratory system and skin.;
Hazard Codes:R36/37/38:Irritating to eyes, respiratory system and skin.;
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (TRIMETHYLSILYLMETHYL)TRIPHENYLPHOSPHONIUM IODIDE

There total 3 articles about (TRIMETHYLSILYLMETHYL)TRIPHENYLPHOSPHONIUM IODIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 16029-98-4
trimethylsilyl iodide

: 19493-09-5
Methylenetriphenylphosphorane

triphenyl(trimethylsilylmethyl)phosphonium iodide: 3739-98-8
triphenyl(trimethylsilylmethyl)phosphonium iodide

Guidance literature:: In toluene; a) -78 deg C, b) r.t., 15-20 h;
DOI:10.1055/s-1992-26227

Reference yield: 80.0%

: 4206-67-1
iodo(trimethylsilyl)methane

: 603-35-0
triphenylphosphine

triphenyl(trimethylsilylmethyl)phosphonium iodide: 3739-98-8
triphenyl(trimethylsilylmethyl)phosphonium iodide

Guidance literature:: In toluene; for 16h; Reflux; Inert atmosphere; Schlenk technique;
DOI:10.1002/anie.201805372

Reference yield:

: 4206-67-1
iodo(trimethylsilyl)methane

: 1779-49-3
Methyltriphenylphosphonium bromide

triphenyl(trimethylsilylmethyl)phosphonium iodide: 3739-98-8
triphenyl(trimethylsilylmethyl)phosphonium iodide

Guidance literature:: Methyltriphenylphosphonium bromide; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;

iodo(trimethylsilyl)methane; In tetrahydrofuran; hexane; at -78 - 0 ℃; Inert atmosphere;
DOI:10.1139/cjc-2013-0337