BIS-(4-NITROPHENYL)-2-NITROPHENYLAMINE

Base Information

• Chemical Name: BIS-(4-NITROPHENYL)-2-NITROPHENYLAMINE
• CAS No.: 117847-23-1
• Molecular Formula: C18H12N4O6
• Molecular Weight: 380.31
• Mol file: 117847-23-1.mol

Synonyms:Bis-(4-nitrophenyl)-2-nitrophenylamine;4-Nitro-N-(2-nitrophenyl)-N-(4-nitrophenyl)aniline;

Chemical Property of BIS-(4-NITROPHENYL)-2-NITROPHENYLAMINE

Chemical Property:

• Appearance/Colour: Yellow Powder
• Vapor Pressure: 4.42E-14mmHg at 25°C
• Melting Point: 225 °C
• Refractive Index: 1.706
• Boiling Point: 594 °C at 760 mmHg
• Flash Point: 313.1 °C
• PSA: 140.70000
• Density: 1.484 g/cm³
• LogP: 6.45060
• Solubility.: Acetone, Acetonitrile, DMF, DMSO, Ethyl Acetate

Purity/Quality:

98%Min ^*data from raw suppliers

Bis-(4-nitrophenyl)-2-nitrophenylamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BIS-(4-NITROPHENYL)-2-NITROPHENYLAMINE

There total 12 articles about BIS-(4-NITROPHENYL)-2-NITROPHENYLAMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

2-nitro-aniline (88-74-4) + 4-Fluoronitrobenzene (350-46-9,178603-76-4) → 4,4',2''-trinitrotriphenylamine (117847-23-1)

Guidance literature:

With potassium carbonate; In dimethyl sulfoxide; at 125 - 130 ℃; for 4.3h;

Reference yield: 76.0%

2-nitro-N-(4-nitrophenyl)benzenamine (612-36-2) + 4-Fluoronitrobenzene (350-46-9,178603-76-4) → 4,4',2''-trinitrotriphenylamine (117847-23-1)

Guidance literature:

With potassium carbonate; In dimethyl sulfoxide; at 125 - 130 ℃; for 4h;

Reference yield: 74.0%

N,N-bis(p-nitrophenyl)amine (1821-27-8) + ortho-nitrofluorobenzene (1493-27-2,127723-77-7) → 4,4',2''-trinitrotriphenylamine (117847-23-1)

Guidance literature:

With potassium tert-butylate; In dimethyl sulfoxide; at 125 - 130 ℃; for 4h;

upstream raw materials:

2-nitro-aniline

4-Fluoronitrobenzene

2-nitro-N-(4-nitrophenyl)benzenamine

N,N-bis(p-nitrophenyl)amine

Refernces

• 1、 Gorvin, John H.. "The Synthesis of Di- and Tri-arylamines through Halogen Displacement by Base-activated Arylamines: Comparison with the Ullmann Condensation". . p. 1331 - 1336. Retrieved 2007/10/02.