{Co(CO)3P(C₆H₅)3}1^(1-)

Base Information

• Chemical Name: {Co(CO)3P(C₆H₅)3}1^(1-)
• CAS No.: 53513-20-5
• Molecular Formula: C₂₁H₁₅CoO₃P
• Molecular Weight: 405.315
• Mol file: 53513-20-5.mol

Synonyms:{Co(CO)3P(C₆H₅)3}1^(1-)

Chemical Property of {Co(CO)3P(C₆H₅)3}1^(1-)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Co(CO)3P(C₆H₅)3}1^(1-)

There total 5 articles about {Co(CO)3P(C₆H₅)3}1^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

CoI(CO)3(P(C6H5)3) (36158-67-5,14376-37-5) + methanolate (3315-60-4) → {Co(CO)3P(C6H5)3}1(1-) (53513-20-5) + CH3OC(O)Co(CO)3P(C6H5)3 (83269-57-2)

Guidance literature:

With 15-crown-5 or 18-crown-6; In tetrahydrofuran; under Ar, ICo(CO)3PPh3 dissolved in THF, Na or K alkoxide and 15-crown-5 or 18-crown-6 resp. added, stirred at 20-25°C for 1 h; n-heptane added, THF evapd. in vac., filtered, evapd. in vac., recrystd. from Et2O/pentane at -78°C;

DOI:10.1021/om00128a006

Reference yield:

CoI(CO)3(P(C6H5)3) (36158-67-5,14376-37-5) + ethanolate (16331-64-9) → {Co(CO)3P(C6H5)3}1(1-) (53513-20-5) + CH3CH2OC(O)Co(CO)3P(C6H5)3 (15244-99-2)

Guidance literature:

With 15-crown-5 or 18-crown-6; In tetrahydrofuran; under Ar, ICo(CO)3PPh3 dissolved in THF, Na or K alkoxide and 15-crown-5 or 18-crown-6 resp. added, stirred at 20-25°C for 1 h; n-heptane added, THF evapd. in vac., filtered, evapd. in vac., recrystd. from Et2O/pentane at -78°C;

DOI:10.1021/om00128a006

Reference yield:

CoI(CO)3(P(C6H5)3) (36158-67-5,14376-37-5) + benzyl oxide ion (45581-66-6) → {Co(CO)3P(C6H5)3}1(1-) (53513-20-5) + C6H5CH2OC(O)Co(CO)3P(C6H5)3 (97170-63-3)

Guidance literature:

With 15-crown-5 or 18-crown-6; In tetrahydrofuran; under Ar, ICo(CO)3PPh3 dissolved in THF, Na or K alkoxide and 15-crown-5 or 18-crown-6 resp. added, stirred at 20-25°C for 1 h; n-heptane added, THF evapd. in vac., filtered, evapd. in vac., recrystd. from Et2O/pentane at -78°C;

DOI:10.1021/om00128a006

upstream raw materials:

CoI(CO)3(P(C₆H₅)3)

methanolate

ethanolate

benzyl oxide ion

Downstream raw materials:

Co₂(CO)6{P(C₄H₉-n)3}2

Co₂(CO)6(P(C₆H₅)3)(P(C₄H₉)3)