C₃₃H₅₇NO₆S₂Si

Base Information

Chemical Name:C₃₃H₅₇NO₆S₂Si
CAS No.:1591927-96-6
Molecular Formula:C₃₃H₅₇NO₆S₂Si
Molecular Weight:656.036
Hs Code.:

C<sub>33</sub>H<sub>57</sub>NO<sub>6</sub>S<sub>2</sub>Si

Synonyms:C₃₃H₅₇NO₆S₂Si

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Chemical Property of C₃₃H₅₇NO₆S₂Si

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Technology Process of C₃₃H₅₇NO₆S₂Si

There total 11 articles about C₃₃H₅₇NO₆S₂Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1591927-56-8
C₂₅H₄₄O₅Si

: 121929-87-1
(R)-1-(4-isopropyl-2-thioxothiazolidin-3-yl)ethanone

: 1591927-96-6
C₃₃H₅₇NO₆S₂Si

Guidance literature:: (R)-1-(4-isopropyl-2-thioxothiazolidin-3-yl)ethanone; With 1-ethyl-piperidine; tin(II) trifluoromethanesulfonate; In dichloromethane; at -50 ℃; for 4.5h; Inert atmosphere;

C₂₅H₄₄O₅Si; In dichloromethane; at -78 ℃; for 12h; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/ol5008179

Reference yield:

: 1591927-46-6
C₁₅H₃₄O₂Si₂

: 1591927-96-6
C₃₃H₅₇NO₆S₂Si

Guidance literature:: Multi-step reaction with 10 steps

1.1: boron trifluoride diethyl etherate / dichloromethane / -95 - -78 °C / Inert atmosphere

2.1: tetramethylammonium triacetoxyborohydride / acetonitrile; acetic acid / 24 h / -40 - -30 °C / Inert atmosphere

3.1: camphor-10-sulfonic acid / dichloromethane; methanol / 4 h / 0 - 20 °C / Inert atmosphere

4.1: camphor-10-sulfonic acid / dichloromethane; methanol / 2 h / 0 °C / Inert atmosphere

5.1: Proton-sponge / dichloromethane / 6 h / 0 - 20 °C / Inert atmosphere

6.1: diisobutylaluminium hydride / dichloromethane; toluene / -10 °C / Inert atmosphere

7.1: Dess-Martin periodane / dichloromethane; tert-butyl alcohol / 0 - 20 °C / Inert atmosphere

8.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 3 h / 0 - 20 °C / Inert atmosphere

9.1: triethylamine; dmap / dichloromethane / 2 h / 0 °C / Inert atmosphere

10.1: tin(II) trifluoromethanesulfonate; 1-ethyl-piperidine / dichloromethane / 4.5 h / -50 °C / Inert atmosphere

10.2: 12 h / -78 °C / Inert atmosphere

With 1-ethyl-piperidine; dmap; tin(II) trifluoromethanesulfonate; camphor-10-sulfonic acid; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; diisobutylaluminium hydride; Dess-Martin periodane; triethylamine; tetramethylammonium triacetoxyborohydride; In tetrahydrofuran; methanol; dichloromethane; acetic acid; toluene; acetonitrile; tert-butyl alcohol; 1.1: |Mukaiyama Aldol Addition;
DOI:10.1021/ol5008179

Reference yield:

: 1591927-49-9
C₃₂H₅₂O₄Si₂

: 1591927-96-6
C₃₃H₅₇NO₆S₂Si

Guidance literature:: Multi-step reaction with 9 steps

1.1: tetramethylammonium triacetoxyborohydride / acetonitrile; acetic acid / 24 h / -40 - -30 °C / Inert atmosphere

2.1: camphor-10-sulfonic acid / dichloromethane; methanol / 4 h / 0 - 20 °C / Inert atmosphere

3.1: camphor-10-sulfonic acid / dichloromethane; methanol / 2 h / 0 °C / Inert atmosphere

4.1: Proton-sponge / dichloromethane / 6 h / 0 - 20 °C / Inert atmosphere

5.1: diisobutylaluminium hydride / dichloromethane; toluene / -10 °C / Inert atmosphere

6.1: Dess-Martin periodane / dichloromethane; tert-butyl alcohol / 0 - 20 °C / Inert atmosphere

7.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 3 h / 0 - 20 °C / Inert atmosphere

8.1: triethylamine; dmap / dichloromethane / 2 h / 0 °C / Inert atmosphere

9.1: tin(II) trifluoromethanesulfonate; 1-ethyl-piperidine / dichloromethane / 4.5 h / -50 °C / Inert atmosphere

9.2: 12 h / -78 °C / Inert atmosphere

With 1-ethyl-piperidine; dmap; tin(II) trifluoromethanesulfonate; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; diisobutylaluminium hydride; Dess-Martin periodane; triethylamine; tetramethylammonium triacetoxyborohydride; In tetrahydrofuran; methanol; dichloromethane; acetic acid; toluene; acetonitrile; tert-butyl alcohol;
DOI:10.1021/ol5008179