Technology Process of 6,6'-Bis-(3,5-bis-benzyloxy-benzyloxy)-2,2'-bis-triisopropylsilanyloxy-[1,1']binaphthalenyl
There total 4 articles about 6,6'-Bis-(3,5-bis-benzyloxy-benzyloxy)-2,2'-bis-triisopropylsilanyloxy-[1,1']binaphthalenyl which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 3 steps
1: imidazole / dimethylformamide / 149 h / Ambient temperature
2: 1.) t-BuLi; 2.) B(OMe)3; 3.) 10percent HCl; 4.) 30percent H2O2 / 1.) THF, -78 deg C, 0.5 h; 2.) THF, -78 deg C to r.t.; 3.) THF, r.t., 0.5 h; 4.) THF
3: 80 percent / NaH / dimethylformamide / 0 deg C to r.t.
With
1H-imidazole; hydrogenchloride; Trimethyl borate; dihydrogen peroxide; tert.-butyl lithium; sodium hydride;
In
N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(98)00616-9
- Guidance literature:
-
Multi-step reaction with 3 steps
1: imidazole / dimethylformamide / 149 h / Ambient temperature
2: 1.) t-BuLi; 2.) B(OMe)3; 3.) 10percent HCl; 4.) 30percent H2O2 / 1.) THF, -78 deg C, 0.5 h; 2.) THF, -78 deg C to r.t.; 3.) THF, r.t., 0.5 h; 4.) THF
3: 80 percent / NaH / dimethylformamide / 0 deg C to r.t.
With
1H-imidazole; hydrogenchloride; Trimethyl borate; dihydrogen peroxide; tert.-butyl lithium; sodium hydride;
In
N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(98)00616-9
