η5-pentamethylcyclopentadienyl(η5-2-(2'-methoxynaphth-1'-yl)-3,4-dimethyl-5-phenylphospholyl)ruthenium(II)

Base Information

Chemical Name:η5-pentamethylcyclopentadienyl(η5-2-(2'-methoxynaphth-1'-yl)-3,4-dimethyl-5-phenylphospholyl)ruthenium(II)
CAS No.:862205-27-4
Molecular Formula:C₃₃H₃₅OPRu
Molecular Weight:579.684
Hs Code.:

Synonyms:η5-pentamethylcyclopentadienyl(η5-2-(2'-methoxynaphth-1'-yl)-3,4-dimethyl-5-phenylphospholyl)ruthenium(II)

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Chemical Property of η5-pentamethylcyclopentadienyl(η5-2-(2'-methoxynaphth-1'-yl)-3,4-dimethyl-5-phenylphospholyl)ruthenium(II)

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Technology Process of η5-pentamethylcyclopentadienyl(η5-2-(2'-methoxynaphth-1'-yl)-3,4-dimethyl-5-phenylphospholyl)ruthenium(II)

There total 1 articles about η5-pentamethylcyclopentadienyl(η5-2-(2'-methoxynaphth-1'-yl)-3,4-dimethyl-5-phenylphospholyl)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 126821-58-7
chloro(pentamethylcyclopentadienyl)ruthenium(II) tetramer

: potassium 2-(2'-methoxynaphth-1'-yl)-3,4-dimethyl-5-phenylphospholide-diglyme

: 862205-27-4
η5-pentamethylcyclopentadienyl(η5-2-(2'-methoxynaphth-1'-yl)-3,4-dimethyl-5-phenylphospholyl)ruthenium(II)

Guidance literature:: In tetrahydrofuran; N2 or Ar atm.; a room temp. THF-soln. of complex was added to a THF-soln. of phospholide, the mixt. was stirred for 30 min, refluxed for 30 min; evapd. to dryness in vac., flash chromy. in pure toluene on silica, crystd. from CH2Cl2-ethanol;
DOI:10.1039/b418926d

Reference yield: 87.0%

: 862205-27-4
η5-pentamethylcyclopentadienyl(η5-2-(2'-methoxynaphth-1'-yl)-3,4-dimethyl-5-phenylphospholyl)ruthenium(II)

: 7732-18-5
water

: 942608-40-4
2-(2'-hydroxynaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II)

Guidance literature:: With lithium diphenylphosphide*2(tetrahydrofuran); In water; byproducts: (C6H5)2PCH3, (C6H5)2PH; (N2 or Ar); using of Schlenk techniques; dissolving of (Me5C5)Ru(C4PMe2PhC10H6OMe) and Ph2PLi*2THF in freeze-thaw cycled THF; reflux for 16 h; monitoring by NMR; treatment with H2O; drying over MgSO4; evapn. to dryness; chromy. on silica (pentane/CH2Cl2,9:1); eluting with CH2Cl2;
DOI:10.1021/om0610905

Reference yield:

: 862205-27-4
η5-pentamethylcyclopentadienyl(η5-2-(2'-methoxynaphth-1'-yl)-3,4-dimethyl-5-phenylphospholyl)ruthenium(II)

: 7732-18-5
water

: 108-88-3,15644-74-3,16713-13-6
toluene

: 2-(2'-hydroxynaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II) toluene solvate

Guidance literature:: With lithium diphenylphosphide*2(tetrahydrofuran); In water; byproducts: (C6H5)2PCH3, (C6H5)2PH; (N2 or Ar); using of Schlenk techniques; dissolving of (C5Me5)Ru(C4PMe2PhC10H6OMe) and Ph2PLi*2THF in freeze-thaw cycled THF; reflux for 16 h; monitoring by NMR; treatment with H2O; drying over MgSO4; evapn. to dryness; crystn. from boiling toluene; elem. anal.;
DOI:10.1021/om0610905