N-phenyl-P,P-bis(3,5-dimethylphenyl)phosphinic amide

Base Information

• Chemical Name: N-phenyl-P,P-bis(3,5-dimethylphenyl)phosphinic amide
• CAS No.: 1454907-93-7
• Molecular Formula: C₂₂H₂₄NOP
• Molecular Weight: 349.412
• Mol file: 1454907-93-7.mol

Synonyms:N-phenyl-P,P-bis(3,5-dimethylphenyl)phosphinic amide

Chemical Property of N-phenyl-P,P-bis(3,5-dimethylphenyl)phosphinic amide

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of N-phenyl-P,P-bis(3,5-dimethylphenyl)phosphinic amide

There total 1 articles about N-phenyl-P,P-bis(3,5-dimethylphenyl)phosphinic amide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethyl bis(3,5-dimethylphenyl)phosphinate (1454908-01-0) + aniline (62-53-3) → N-phenyl-P,P-bis(3,5-dimethylphenyl)phosphinic amide (1454907-93-7)

Guidance literature:

ethyl bis(3,5-dimethylphenyl)phosphinate; With phosphorus pentachloride; trichlorophosphate; at 0 - 110 ℃; for 4h; Inert atmosphere;

aniline; In acetonitrile; at 50 ℃; for 1h;

DOI:10.1039/c3cc44995e

Reference yield: 72.0%

N-phenyl-P,P-bis(3,5-dimethylphenyl)phosphinic amide (1454907-93-7) + Methyl phenyldiazoacetate (22979-35-7) → C31H32NO3P

Guidance literature:

With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; copper(II) bis(trifluoromethanesulfonate); In 1,2-dichloro-ethane; at 60 ℃; for 0.5h;

DOI:10.1002/bkcs.12040

Reference yield: 60.0%

4,4'-dimethoxydiphenylacetylene (2132-62-9) + N-phenyl-P,P-bis(3,5-dimethylphenyl)phosphinic amide (1454907-93-7) → N-phenyl-1-(3,5-dimethylphenyl)-3,4-di(p-methoxyphenyl)-1,2-dihydro-5,7-dimethylbenz[c-1,2]azaphosphinine 1-oxide (1454909-12-6)

Guidance literature:

With potassium dihydrogenphosphate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver carbonate; In tert-butyl alcohol; for 30h;

upstream raw materials:

ethyl bis(3,5-dimethylphenyl)phosphinate

aniline

Downstream raw materials:

N-phenyl-1-(3,5-dimethylphenyl)-3,4-di(p-methoxyphenyl)-1,2-dihydro-5,7-dimethylbenz[c-1,2]azaphosphinine 1-oxide