phenylacetaldehyde-2-d

Base Information

• Chemical Name: phenylacetaldehyde-2-d
• CAS No.: 119333-55-0
• Molecular Formula: C₈H₈O
• Molecular Weight: 121.143
• Mol file: 119333-55-0.mol

Synonyms:phenylacetaldehyde-2-d

Chemical Property of phenylacetaldehyde-2-d

Chemical Property:

Purity/Quality:

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Technology Process of phenylacetaldehyde-2-d

There total 11 articles about phenylacetaldehyde-2-d which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Phenylacetylene-d1 (3240-11-7) → phenylacetaldehyde-2-d (119333-55-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) 9-BBN; 2.) CH₃COOH / 1.) THF, a.) 0 deg C, 1 h; b.) 4 deg C, 24 h; 2.) THF, 0 deg C, 2 h

2: LiOCl, pentafluoroiodosylbenzene (F₅PhIO) / (tetrakis(pentafluorophenyl)porphyrinato)iron(III) chloride (FePFPCl) / CH₂Cl₂

With 9-borabicyclo[3.3.1]nonane dimer; lithium hypochlorite; 1,2,3,4,5-pentafluoro-6-iodosylbenzene; acetic acid; 5,10,15,20-tetrakis(pentafluorophenyl)-21H,23H-porphyrin iron(III) chloride; In dichloromethane;

DOI:10.1021/ja00270a016

Reference yield:

(Z)-β-deuteriostyrene (21370-59-2) → phenylacetaldehyde-2-d (119333-55-0) + cis-β-deuterio-styrene oxide (29430-01-1,101977-04-2,101977-05-3,108645-29-0,119365-75-2) + trans-β-deuteriostyrene oxide (29430-01-1,101977-04-2,101977-05-3,108645-29-0,119365-75-2)

Guidance literature:

With lithium hypochlorite; 1,2,3,4,5-pentafluoro-6-iodosylbenzene; 5,10,15,20-tetrakis(pentafluorophenyl)-21H,23H-porphyrin iron(III) chloride; In dichloromethane; Yield given. Yields of byproduct given;

DOI:10.1021/ja00270a016

Reference yield:

(Z)-β-deuteriostyrene (21370-59-2) → [1-2H1]-2-phenylethanal (71964-68-6) + phenylacetaldehyde-2-d (119333-55-0) + cis-β-deuterio-styrene oxide (29430-01-1,101977-04-2,101977-05-3,108645-29-0,119365-75-2) + trans-β-deuteriostyrene oxide (29430-01-1,101977-04-2,101977-05-3,108645-29-0,119365-75-2)

Guidance literature:

With lithium hypochlorite; 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride; stereochemistry of epoxidation with other catalyst;

DOI:10.1021/ja00270a016

upstream raw materials:

rac-(β,β-²H₂)styrene oxide

cis-β-deuterio-styrene oxide

trans-β-deuteriostyrene oxide

10-[(Z)-2-phenylethenyl]-10H-phenothiazine