Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-[(2R,3S,4R,5R,6R)-5-acetylamino-6-azido-2-benzyloxymethyl-4-((2S,3S,4R,5R)-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yloxy]-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester

Base Information

Chemical Name:Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-[(2R,3S,4R,5R,6R)-5-acetylamino-6-azido-2-benzyloxymethyl-4-((2S,3S,4R,5R)-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yloxy]-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester
CAS No.:397865-62-2
Molecular Formula:C₆₀H₆₈N₄O₁₇
Molecular Weight:1117.22
Hs Code.:

Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-[(2R,3S,4R,5R,6R)-5-acetylamino-6-azido-2-benzyloxymethyl-4-((2S,3S,4R,5R)-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yloxy]-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester

Synonyms:Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-[(2R,3S,4R,5R,6R)-5-acetylamino-6-azido-2-benzyloxymethyl-4-((2S,3S,4R,5R)-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yloxy]-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester

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Chemical Property of Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-[(2R,3S,4R,5R,6R)-5-acetylamino-6-azido-2-benzyloxymethyl-4-((2S,3S,4R,5R)-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yloxy]-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester

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Technology Process of Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-[(2R,3S,4R,5R,6R)-5-acetylamino-6-azido-2-benzyloxymethyl-4-((2S,3S,4R,5R)-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yloxy]-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester

There total 6 articles about Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-[(2R,3S,4R,5R,6R)-5-acetylamino-6-azido-2-benzyloxymethyl-4-((2S,3S,4R,5R)-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yloxy]-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

: 169393-72-0
2,3,4-tri-O-acetyl-6-O-benzyl-α,β-D-galactopyranosyl trichloroacetimidate

: 397865-61-1
N-[(2R,3R,4R,5S,6R)-2-Azido-6-benzyloxymethyl-5-hydroxy-4-((2S,3S,4R,5R)-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide

: 397865-62-2
Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-[(2R,3S,4R,5R,6R)-5-acetylamino-6-azido-2-benzyloxymethyl-4-((2S,3S,4R,5R)-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yloxy]-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -15 ℃; for 48h;
DOI:10.1002/1521-3773(20011015)40:20<3836::AID-ANIE3836>3.0.CO;2-5

Reference yield:

: 108646-05-5
(3S,4R,5R)-tetrahydro-2H-pyran-2,3,4,5-tetrayl tetraacetate

: 397865-62-2
Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-[(2R,3S,4R,5R,6R)-5-acetylamino-6-azido-2-benzyloxymethyl-4-((2S,3S,4R,5R)-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yloxy]-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 49 percent / BF₃*Et₂O / CH₂Cl₂ / -15 °C

2: 88 percent / NaH / dimethylformamide / 0 °C

3: 57 percent / CuBr₂; Bu₄NBr / CH₂Cl₂; dimethylformamide / 20 °C

4: 68 percent / NaCNBH₃; HCl / tetrahydrofuran; diethyl ether / 0 °C

5: 49 percent / TMSOTf / CH₂Cl₂ / 48 h / -15 °C

With hydrogenchloride; trimethylsilyl trifluoromethanesulfonate; boron trifluoride diethyl etherate; tetrabutylammomium bromide; sodium hydride; sodium cyanoborohydride; copper(ll) bromide; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/1521-3773(20011015)40:20<3836::AID-ANIE3836>3.0.CO;2-5

Reference yield:

: 397865-58-6
ethylthio-tetra-O-acetyl-α,β-D-arabinopyranoside

: 397865-62-2
Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-[(2R,3S,4R,5R,6R)-5-acetylamino-6-azido-2-benzyloxymethyl-4-((2S,3S,4R,5R)-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yloxy]-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 88 percent / NaH / dimethylformamide / 0 °C

2: 57 percent / CuBr₂; Bu₄NBr / CH₂Cl₂; dimethylformamide / 20 °C

3: 68 percent / NaCNBH₃; HCl / tetrahydrofuran; diethyl ether / 0 °C

4: 49 percent / TMSOTf / CH₂Cl₂ / 48 h / -15 °C

With hydrogenchloride; trimethylsilyl trifluoromethanesulfonate; tetrabutylammomium bromide; sodium hydride; sodium cyanoborohydride; copper(ll) bromide; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/1521-3773(20011015)40:20<3836::AID-ANIE3836>3.0.CO;2-5