ZINC;propan-2-olate

Base Information

• Chemical Name: ZINC;propan-2-olate
• CAS No.: 13282-39-8
• Molecular Formula: 2C₃H₇O*Zn
• Molecular Weight: 183.566
• European Community (EC) Number: 811-459-9
• Mol file: 13282-39-8.mol

Synonyms:zinc;propan-2-olate;13282-39-8;SCHEMBL453861;zinc(2+) bis(propan-2-olate);HKIRVJCLEHCVAL-UHFFFAOYSA-N

Chemical Property of ZINC;propan-2-olate

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 182.028521
• Heavy Atom Count: 9
• Complexity: 10.8

Purity/Quality:

98% ^*data from raw suppliers

Zinc i-propoxide, 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)[O-].CC(C)[O-].[Zn+2]

Technology Process of ZINC;propan-2-olate

There total 4 articles about ZINC;propan-2-olate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 1.0%

[(N,N'-dibenzyl-2-amino-4-iminopent-2-ene(-1H))Zn(isopropanolate)] (1226915-10-1) → [(N,N'-dibenzyl-2-amino-4-iminopent-2-ene(-1H))2Zn] (1226915-05-4) + zinc diisopropanolate (13282-39-8)

Guidance literature:

With rac-lactide; In dichloromethane-d2; (N2); using Schlenk techniques; addn. of ((CH3)2CHO)Zn(PhCH2NC(Me)CHC(Me)NCH2Ph) in CD2Cl2 to soln. of rac-lactide in CD2Cl2 in NNR tube; monitoring by NMR;

DOI:10.1021/om100154w

Reference yield:

zinc bis(tetra(isopropyl))orthovanadate → vanadium(V) oxytriisopropoxide (5588-84-1) + zinc diisopropanolate (13282-39-8)

Guidance literature:

heating to about 60°C (Ar);

Reference yield:

diethylzinc (557-20-0) + isopropyl alcohol (67-63-0,8013-70-5) → zinc diisopropanolate (13282-39-8)

Guidance literature:

In n-heptane; for 1h; Heating / reflux;

upstream raw materials:

diethylzinc

isopropyl alcohol

[(N,N'-dibenzyl-2-amino-4-iminopent-2-ene(-1H))Zn(isopropanolate)]

Downstream raw materials:

diethylzinc