3,5-Methano-2H-cyclopenta[b]furan-2-one, 6-bromohexahydro-, [3S-(3alpha,3abeta,5alpha,6beta,6abeta)]-

Base Information

Chemical Name:3,5-Methano-2H-cyclopenta[b]furan-2-one, 6-bromohexahydro-, [3S-(3alpha,3abeta,5alpha,6beta,6abeta)]-
CAS No.:123536-32-3
Molecular Formula:C₈H₉BrO₂
Molecular Weight:217.062
Hs Code.:
DSSTox Substance ID:DTXSID401128461

Synonyms:DTXSID401128461;123536-32-3;3,5-Methano-2H-cyclopenta[b]furan-2-one, 6-bromohexahydro-, [3S-(3alpha,3abeta,5alpha,6beta,6abeta)]-

Suppliers and Price of 3,5-Methano-2H-cyclopenta[b]furan-2-one, 6-bromohexahydro-, [3S-(3alpha,3abeta,5alpha,6beta,6abeta)]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3,5-Methano-2H-cyclopenta[b]furan-2-one, 6-bromohexahydro-, [3S-(3alpha,3abeta,5alpha,6beta,6abeta)]-

Chemical Property:

XLogP3:1.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:215.97859
Heavy Atom Count:11
Complexity:228

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1C2CC3C1C(C2Br)OC3=O
Isomeric SMILES:C1[C@H]2C[C@H]3[C@@H]1[C@@H]([C@H]2Br)OC3=O

Technology Process of 3,5-Methano-2H-cyclopenta[b]furan-2-one, 6-bromohexahydro-, [3S-(3alpha,3abeta,5alpha,6beta,6abeta)]-

There total 4 articles about 3,5-Methano-2H-cyclopenta[b]furan-2-one, 6-bromohexahydro-, [3S-(3alpha,3abeta,5alpha,6beta,6abeta)]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 934-30-5,1195-12-6,20507-53-3,58001-99-3,67999-50-2,67999-53-5,74645-32-2,108266-75-7,120-74-1
5-norbornene-endo-2-carboxylic acid

: 263713-64-0
2,6,6-trimethyl-5,5-bis(trimethylsilyl)-5,6-disilaheptan-2-ol

: 934-30-5,1195-12-6,20507-53-3,58001-99-3,67999-50-2,67999-53-5,74645-32-2,108266-75-7,120-74-1
5-norbornene-endo-2-carboxylic acid

: 741291-97-4
C₁₆H₁₇NO₄

: 16512-03-1,84893-91-4,87305-14-4,123536-32-3
endo-2-carboxy-exo-5-bromo-endo-6-hydroxynorbornane lactone

: 14948-68-6
(1S,2S,3S,6S,7R)-2-Iodo-4-oxa-tricyclo[4.2.1.0^3,7]nonan-5-one

: 84893-91-4
6-bromohexahydro-2H-3,5-methanocyclopenta[b]furan-2-one

Guidance literature:: 5-norbornene-endo-2-carboxylic acid; With oxalyl dichloride; In dichloromethane; at 25 ℃; for 6h;

12-(tert-butyldimethylsilanyloxy)dodecan-1-ol; With pyridine; In tetrahydrofuran; at 25 ℃;
DOI:10.1021/ma049647k

Reference yield: 88.0%

: 934-30-5,1195-12-6,20507-53-3,58001-99-3,67999-50-2,67999-53-5,74645-32-2,108266-75-7,120-74-1
5-norbornene-endo-2-carboxylic acid

: 263713-64-0
2,6,6-trimethyl-5,5-bis(trimethylsilyl)-5,6-disilaheptan-2-ol

: 934-30-5,1195-12-6,20507-53-3,58001-99-3,67999-50-2,67999-53-5,74645-32-2,108266-75-7,120-74-1
5-norbornene-endo-2-carboxylic acid

: 741291-97-4
C₁₆H₁₇NO₄

: 16512-03-1,84893-91-4,87305-14-4,123536-32-3
endo-2-carboxy-exo-5-bromo-endo-6-hydroxynorbornane lactone

: 14948-68-6
(1S,2S,3S,6S,7R)-2-Iodo-4-oxa-tricyclo[4.2.1.0^3,7]nonan-5-one

: 84893-91-4
6-bromohexahydro-2H-3,5-methanocyclopenta[b]furan-2-one

: 250589-01-6
2,6,6-Trimethyl-5,5-bis(trimethylsilyl)-5,6-disilahept-2-yl Bicyclo[2.2.1]hept-5-ene-2-carboxylate

Guidance literature:: 5-norbornene-endo-2-carboxylic acid; With oxalyl dichloride; In dichloromethane; at 25 ℃; for 6h;

12-(tert-butyldimethylsilanyloxy)dodecan-1-ol; With pyridine; In tetrahydrofuran; at 25 ℃;
DOI:10.1021/ma049647k

Reference yield: 75.0%

: 120-74-1,934-30-5,1195-12-6,20507-53-3,58001-99-3,67999-50-2,67999-53-5,74645-32-2,108266-75-7
(1S,2S,4S)-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid

: 123536-32-3
6-bromohexahydro-2H-3,5-methanocyclopenta[b]furan-2-one

Guidance literature:: With N-Bromosuccinimide; methyl 2-methyl-1H-indole-3-carboxylate; In n-heptane; at 25 ℃; for 22h;
DOI:10.1021/acscatal.5b01182