Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid

Base Information

Chemical Name:Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid
CAS No.:120-74-1
Deprecated CAS:193277-13-3,1404083-86-8
Molecular Formula:C₈H₁₀O₂
Molecular Weight:138.166
Hs Code.:29162090
European Community (EC) Number:204-422-8,624-387-6
NSC Number:155661,152348
DSSTox Substance ID:DTXSID80883313
Nikkaji Number:J297.767B
ChEMBL ID:CHEMBL276474
Mol file:120-74-1.mol

Synonyms:120-74-1;5-Norbornene-2-carboxylic acid;Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid;Norbornenecarboxylic acid;exo-5-Norbornene-2-carboxylic acid;5-Norbornene-2-carboxylic acid, exo-;NSC 155661;5-Norbornene-2-carboxylic acid (8CI);BRN 3196451;Bicyclo(2.2.1)hept-2-ene-5-carboxylic acid;Bicyclo[2.2.1]-5-heptene-2-carboxylic acid;Bicyclo[2.2.1]hept-2-ene-5-carboxylic acid;norborn-5-ene-2-carboxylic acid;EINECS 204-422-8;NSC 152348;AI3-51329;Bicyclo(2.2.1)hept-5-ene-2-carboxylic acid;4-09-00-00224 (Beilstein Handbook Reference);Bicyclo(2.2.1)hept-5-ene-2-carboxylic acid, exo-;Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, exo-;934-30-5;exo-Bicyclo(2.2.1)hept-5-ene-2-carboxylic acid;67999-53-5;exo-Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid;5-norbornene-carboxylic acid;SCHEMBL75505;5-norbomene-2-carboxylic acid;5-norbornen-2-carboxylic acid;2-norbornene-5-carboxylic acid;5-norbornene 2-carboxylic acid;CHEMBL276474;WLN: L55 A CUTJ FVQ;2-norborn-5-ene carboxylic acid;DTXSID80883313;MFCD00085356;NSC152348;NSC155661;5-Norbornene-2-carboxylic acid 97%;AKOS000120886;AKOS016311792;AKOS025243184;AC-4854;CS-W016495;NSC-152348;NSC-155661;SB45385;SB45624;BP-24389;LS-97175;5-bicyclo[2,2,1]heptene-2-carboxylic acid;AM20080145;BB 0216344;BB 0301297;Bicyclo[2.2.1]hept-5-ene-2-carboxylicacid;FT-0622951;FT-0678039;N0667;bicyclo[2,2,1]hept-5-ene-2-carboxylic acid;bicyclo[2.2.1]hept-2-ene-6-carboxylic acid;bicyclo[2.2.1]hept-5-ene-3-carboxylic acid;EN300-21280;A804582;J-802156;(1S,4S,5S)-bicyclo[2.2.1]hept-2-ene-5-carboxylate;F3095-4888;Z104495016

Suppliers and Price of Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
rac-(1R,2R,4R)-Bicyclo[2.2.1]hept-5-ene-2-carboxylicAcid
50mg
$ 45.00

TCI Chemical
5-Norbornene-2-carboxylic Acid >98.0%(GC)(T)
5g
$ 21.00

TCI Chemical
5-Norbornene-2-carboxylic Acid >98.0%(GC)(T)
25g
$ 55.00

Sigma-Aldrich
5-Norbornene-2-carboxylic acid, mixture of endo and exo, predominantly endo 98%
25ml
$ 95.20

Matrix Scientific
Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid 95+%
100g
$ 221.00

Frontier Specialty Chemicals
5-Norbornene-2-carboxylicacid,98%,mixtureofendoandexo,predominantlyendo
5g
$ 21.00

Frontier Specialty Chemicals
5-Norbornene-2-carboxylicacid,98%,mixtureofendoandexo,predominantlyendo
25g
$ 85.00

ChemScene
Bicyclo[2.2.1]hept-5-ene-2-carboxylicacid >97.0%
100g
$ 66.00

Arctom
Bicyclo[2.2.1]hept-5-ene-2-carboxylicacid 97%
10g
$ 10.00

Arctom
Bicyclo[2.2.1]hept-5-ene-2-carboxylicacid 97%
5g
$ 7.00

Total 141 raw suppliers

Chemical Property of Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid

Chemical Property:

Vapor Pressure:0.007mmHg at 25°C
Melting Point:32.5-35 °C
Refractive Index:n20/D 1.494(lit.)
Boiling Point:266.653 °C at 760 mmHg
PKA:4.63±0.20(Predicted)
Flash Point:120.763 °C
PSA：37.30000
Density:1.247 g/cm³
LogP:1.28320
Storage Temp.:Sealed in dry,Room Temperature
Water Solubility.:Not miscible with water.
XLogP3:1.2
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:138.068079557
Heavy Atom Count:10
Complexity:195

Purity/Quality:

99% ^*data from raw suppliers

rac-(1R,2R,4R)-Bicyclo[2.2.1]hept-5-ene-2-carboxylicAcid ^*data from reagent suppliers

Safty Information:

Pictogram(s): C
Hazard Codes:C
Statements: 34
Safety Statements: 26-36/37/39-45-27

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:C1C2CC(C1C=C2)C(=O)O
Uses rac-(1R,2R,4R)-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid is a useful research chemical. 5-Norbornene-2-carboxylic acid is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff.

Technology Process of Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid

There total 142 articles about Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 934-30-5,1195-12-6,20507-53-3,58001-99-3,67999-50-2,67999-53-5,74645-32-2,108266-75-7,120-74-1
5-norbornene-endo-2-carboxylic acid

Guidance literature:

Reference yield: 97.9%

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 79-10-7
acrylic acid

: 934-30-5,1195-12-6,20507-53-3,58001-99-3,67999-50-2,67999-53-5,74645-32-2,108266-75-7,120-74-1
5-norbornene-endo-2-carboxylic acid

Guidance literature:: In benzene;

Reference yield: 95.0%

: 637033-13-7
(1S,2S,4S)-2-(2-hydroxy-2-methylpropanoyl)bicyclo[2.2.1]hept-5-ene

: 120-74-1,934-30-5,1195-12-6,20507-53-3,58001-99-3,67999-50-2,67999-53-5,74645-32-2,108266-75-7
(1S,2S,4S)-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid

: 67-64-1
acetone

Guidance literature:: With ammonium cerium (IV) nitrate; In water; acetonitrile; at 0 ℃; optical yield given as %ee; Inert atmosphere;
DOI:10.1021/jo9023039