nickel(II) 2-nitro-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

Base Information

Chemical Name:nickel(II) 2-nitro-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin
CAS No.:412348-11-9
Molecular Formula:C₇₆H₉₁N₅NiO₂
Molecular Weight:1165.28
Hs Code.:

Synonyms:nickel(II) 2-nitro-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

Suppliers and Price of nickel(II) 2-nitro-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of nickel(II) 2-nitro-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of nickel(II) 2-nitro-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

There total 1 articles about nickel(II) 2-nitro-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 157795-60-3
5,10,15,20-tetrakis(3,5-di-tert-butyl-tetraphenylporphyrin) nickel

: lithium nitrate

: 412348-11-9
nickel(II) 2-nitro-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

Guidance literature:: With acetic acid; acetic anhydride; In chloroform; acetic acid; soln. of LiNO3 in acetic acid/acetanhydride added to warm soln. of nickel tetraaryl porphyrin in CHCl3, stirred for 1.5 h; mixt. neutralized with aq. NaHCO3, washed with water, organic phase sepd. and evapd., crystn. from CH2Cl2-MeOH;
DOI:10.1021/ic035203d

Reference yield: 88.0%

: 412348-11-9
nickel(II) 2-nitro-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

: 72047-94-0
[2-(acetoxymethyl)prop-2-enyl]trimethylsilane

: 7732-18-5
water

: nickel(II) 2,3-(β-methylenepropano)-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin dihydrate

Guidance literature:: With Pd(O₂CCH₃)2; triisopropyl phosphite; In tetrahydrofuran; (air-free conditions); a mixt. of Pd salt and triisopropyl phosphite in THF stirred at room temp. for 30 min, Ni complex and Si compd. added, heated at 90°C for 2 d and at 100°C for 2 d; evapd. (vac.), chromd. (silica gel, CH2Cl2/cyclohexane); elem. anal.;
DOI:10.1021/ic062303l

Reference yield:

: 412348-11-9
nickel(II) 2-nitro-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

: 72047-94-0
[2-(acetoxymethyl)prop-2-enyl]trimethylsilane

: 412348-30-2
nickel(II) 2,3-(β-methylenepropano)-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

Guidance literature:: With catalyst: palladium⁽⁰⁾; In not given; byproducts: nitrous acid; strict air-free conditions; 2 d, 90°C, Pd(0) prepd. in situ; further heating at 100°C, 2 d;
DOI:10.1039/b107732e