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(2S,3R,4R,5S)-N,N-dimethyl-2-azido-3-benzyloxy-6-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxymethyl)-4-(p-methoxybenzyloxy)-5-[2-(trimethylsilyl)ethoxymethoxy]hexanoamide

Base Information Edit
  • Chemical Name:(2S,3R,4R,5S)-N,N-dimethyl-2-azido-3-benzyloxy-6-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxymethyl)-4-(p-methoxybenzyloxy)-5-[2-(trimethylsilyl)ethoxymethoxy]hexanoamide
  • CAS No.:344615-50-5
  • Molecular Formula:C52H78N4O8Si3
  • Molecular Weight:971.47
  • Hs Code.:
  • Mol file:344615-50-5.mol
(2S,3R,4R,5S)-N,N-dimethyl-2-azido-3-benzyloxy-6-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxymethyl)-4-(p-methoxybenzyloxy)-5-[2-(trimethylsilyl)ethoxymethoxy]hexanoamide

Synonyms:(2S,3R,4R,5S)-N,N-dimethyl-2-azido-3-benzyloxy-6-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxymethyl)-4-(p-methoxybenzyloxy)-5-[2-(trimethylsilyl)ethoxymethoxy]hexanoamide

Suppliers and Price of (2S,3R,4R,5S)-N,N-dimethyl-2-azido-3-benzyloxy-6-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxymethyl)-4-(p-methoxybenzyloxy)-5-[2-(trimethylsilyl)ethoxymethoxy]hexanoamide
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Chemical Property of (2S,3R,4R,5S)-N,N-dimethyl-2-azido-3-benzyloxy-6-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxymethyl)-4-(p-methoxybenzyloxy)-5-[2-(trimethylsilyl)ethoxymethoxy]hexanoamide Edit
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Technology Process of (2S,3R,4R,5S)-N,N-dimethyl-2-azido-3-benzyloxy-6-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxymethyl)-4-(p-methoxybenzyloxy)-5-[2-(trimethylsilyl)ethoxymethoxy]hexanoamide

There total 1 articles about (2S,3R,4R,5S)-N,N-dimethyl-2-azido-3-benzyloxy-6-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxymethyl)-4-(p-methoxybenzyloxy)-5-[2-(trimethylsilyl)ethoxymethoxy]hexanoamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
(2S,3R,4R,5S)-N,N-dimethyl-2-azido-3-benzyloxy-6-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxymethyl)-4-(p-methoxybenzyloxy)-5-[2-(trimethylsilyl)ethoxymethoxy]hexanoamide; With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water; at 20 ℃; for 3h;
With pyridinium p-toluenesulfonate; In toluene; at 70 ℃; for 24h;
DOI:10.1016/S0040-4020(02)01058-X
Guidance literature:
Multi-step reaction with 7 steps
1.1: 2,3-dichloro-5,6-dicyano-1,4-benzoquinone / CH2Cl2; H2O / 3 h / 20 °C
1.2: 62 percent / pyridinium p-toluenesulfonate / toluene / 24 h / 70 °C
2.1: 61 percent / NaBrO3; NaHSO3 / ethyl acetate; H2O / 1 h / 20 °C
3.1: H2 / Pd/C / ethyl acetate / 14 h / 20 °C
4.1: 0.24 g / 4-(dimethylamino)pyridine; triethylamine / CH2Cl2 / 2 h / 20 °C
5.1: 87 percent / H2SO4 / H2O; acetone / 13 h / 20 °C
6.1: Dess-Martin periodinane / CH2Cl2 / 1.5 h / 20 °C
7.1: 0.12 g / CrCl2 / tetrahydrofuran / 3 h / 0 - 20 °C
With chromium dichloride; dmap; sodium bromate; sulfuric acid; hydrogen; Dess-Martin periodane; sodium hydrogensulfite; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; palladium on activated charcoal; In tetrahydrofuran; dichloromethane; water; ethyl acetate; acetone;
DOI:10.1016/S0040-4020(02)01058-X
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