2-azido-2-methylbutyl benzoate

Base Information

• Chemical Name: 2-azido-2-methylbutyl benzoate
• CAS No.: 1009091-33-1
• Molecular Formula: C₁₂H₁₅N₃O₂
• Molecular Weight: 233.27
• Mol file: 1009091-33-1.mol

Synonyms:2-azido-2-methylbutyl benzoate

Chemical Property of 2-azido-2-methylbutyl benzoate

Chemical Property:

Purity/Quality:

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Technology Process of 2-azido-2-methylbutyl benzoate

There total 3 articles about 2-azido-2-methylbutyl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

isoamyl benzoate (94-46-2) → 2-azido-2-methylbutyl benzoate (1009091-33-1)

Guidance literature:

With tris(2,2'-bipyridyl)ruthenium dichloride; 1-azido-1λ³-benzo[d][1,2]iodaoxol-3(1H)-one; at 20 ℃; for 24h; Irradiation; Inert atmosphere;

DOI:10.1039/c5sc04169d

Reference yield: 70.0%

3-methylbut-3-enyl benzoate (5205-12-9) → 2-azido-2-methylbutyl benzoate (1009091-33-1)

Guidance literature:

With tert.-butylhydroperoxide; tetramethyldisiloxane; cobalt(II) tetrafluoroborate; In ethanol; at 23 ℃; for 4h;

DOI:10.1055/s-2007-1000817

Reference yield: 43.0%

isoamyl benzoate (94-46-2) → 2-azido-2-methylbutyl benzoate (1009091-33-1) + 3-chloro-3-methylbutyl benzoate

Guidance literature:

With (2,6-bis((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine)FeCl₂(N₃); 1-azido-1λ³-benzo[d][1,2]iodaoxol-3(1H)-one; In acetonitrile; at 50 ℃; for 24h; Inert atmosphere; Glovebox;

DOI:10.1021/jacs.1c07330

upstream raw materials:

3-methylbut-3-enyl benzoate

isoamyl benzoate