C₂₂H₃₈O₄Si

Base Information

Chemical Name:C₂₂H₃₈O₄Si
CAS No.:1610030-08-4
Molecular Formula:C₂₂H₃₈O₄Si
Molecular Weight:394.627
Hs Code.:

C<sub>22</sub>H<sub>38</sub>O<sub>4</sub>Si

Synonyms:C₂₂H₃₈O₄Si

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Chemical Property of C₂₂H₃₈O₄Si

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Technology Process of C₂₂H₃₈O₄Si

There total 2 articles about C₂₂H₃₈O₄Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 1453868-10-4
(3S,4R)-5-((4-methoxybenzyl)oxy)-4-methylpentane-1,3-diol

: 85272-31-7
di-tert-butylsilyl bis(trifluoromethanesulfonate)

: 1610030-08-4
C₂₂H₃₈O₄Si

Guidance literature:: With pyridine; In dichloromethane; at 0 - 20 ℃; for 17h; Inert atmosphere;
DOI:10.1021/ol5006856

Reference yield:

: {(2R,3R)-3-[(R)-2-(4-Methoxy-benzyloxy)-1-methyl-ethyl]-oxiranyl}-methanol

: 1610030-08-4
C₂₂H₃₈O₄Si

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium bis(2-methoxyethoxy)aluminium dihydride / dichloromethane; toluene / 22 h / 0 - 20 °C / Inert atmosphere

1.2: 1 h / 20 °C

2.1: pyridine / dichloromethane / 17 h / 0 - 20 °C / Inert atmosphere

With pyridine; sodium bis(2-methoxyethoxy)aluminium dihydride; In dichloromethane; toluene;
DOI:10.1021/ol5006856

Reference yield:

: 1610030-08-4
C₂₂H₃₈O₄Si

: C₃₅H₆₂O₇Si

Guidance literature:: Multi-step reaction with 20 steps

1.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 2 h / 20 °C

2.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 2 h / 20 °C / Inert atmosphere

3.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / tetrahydrofuran / 168 h / 20 °C

4.1: diisobutylaluminium hydride / tetrahydrofuran; hexane / 1.5 h / -72 °C / Inert atmosphere

5.1: titanium(IV) isopropylate; diethyl (2R,3R)-tartrate / dichloromethane / 0.75 h / -30 °C / Molecular sieve; Inert atmosphere

5.2: 15 h / -30 °C / Molecular sieve; Inert atmosphere

6.1: pyridine; tributylphosphine / 6.5 h / 20 - 50 °C / Inert atmosphere

7.1: dichloromethane; hexane / 19 h / -50 °C / Inert atmosphere

8.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 50 h / 20 °C / Inert atmosphere

9.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.75 h / 0 °C

10.1: lithium hexamethyldisilazane / tetrahydrofuran / 6 h / 0 - 20 °C / Inert atmosphere

11.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 18 h / 20 °C

12.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 2 h / 20 °C

13.1: (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; borane-THF / toluene; tetrahydrofuran / 1.17 h / -40 °C / Inert atmosphere

14.1: titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate / dichloromethane / 18 h / -30 °C / Molecular sieve; Inert atmosphere

15.1: copper(l) iodide / diethyl ether / 23 h / -70 - 20 °C / Inert atmosphere

15.2: 4 h / 20 °C

16.1: aluminum (III) chloride / 1 h / 0 °C / Inert atmosphere

17.1: toluene-4-sulfonic acid / dichloromethane / 2 h / 20 °C / Inert atmosphere

18.1: pyridinium p-toluenesulfonate / 0.33 h / 20 °C / Inert atmosphere

19.1: N,N,N,N,-tetramethylethylenediamine / diethyl ether / 2 h / 20 °C / Inert atmosphere

20.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 0.33 h / 20 °C / Inert atmosphere

With pyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; aluminum (III) chloride; copper(l) iodide; tetrapropylammonium perruthennate; borane-THF; diethyl (2R,3R)-tartrate; L-(+)-diisopropyl tartrate; N,N,N,N,-tetramethylethylenediamine; tributylphosphine; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; toluene-4-sulfonic acid; 4-methylmorpholine N-oxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium hexamethyldisilazane; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; water; dimethyl sulfoxide; toluene; 3.1: |Wittig Olefination / 5.1: |Sharpless Asymmetric Epoxidation / 5.2: |Sharpless Asymmetric Epoxidation / 13.1: |Corey-Bakshi-Shibata Reduction / 14.1: |Sharpless Asymmetric Epoxidation;
DOI:10.1021/ol5006856