[([2,6-(i)Pr₂C₆H₃NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr₂C₆H₃(fluorobenzene)][B(C₆F₅)4]

Base Information

• Chemical Name: [([2,6-(i)Pr₂C₆H₃NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr₂C₆H₃(fluorobenzene)][B(C₆F₅)4]
• CAS No.: 874919-67-2
• Molecular Formula: C₂₄BF₂₀*C₅₃H₇₅FN₃Ti
• Molecular Weight: 1500.12
• Mol file: 874919-67-2.mol

Synonyms:[([2,6-(i)Pr₂C₆H₃NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr₂C₆H₃(fluorobenzene)][B(C₆F₅)4]

Chemical Property of [([2,6-(i)Pr₂C₆H₃NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr₂C₆H₃(fluorobenzene)][B(C₆F₅)4]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [([2,6-(i)Pr₂C₆H₃NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr₂C₆H₃(fluorobenzene)][B(C₆F₅)4]

There total 2 articles about [([2,6-(i)Pr₂C₆H₃NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr₂C₆H₃(fluorobenzene)][B(C₆F₅)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

fluorobenzene (462-06-6) + ([2,6-(i)Pr2C6H3NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr2C6H3(Cl) (859157-00-9) + triethylsilylium tetrakis(pentafluorophenyl), toluene adduct (148354-27-2) → [([2,6-(i)Pr2C6H3NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr2C6H3(fluorobenzene)][B(C6F5)4] (874919-67-2)

Guidance literature:

In fluorobenzene;

DOI:10.1021/ja0566026

Reference yield:

fluorobenzene (462-06-6) + [([2,6-(i)Pr2C6H3NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr2C6H3(η1-C6H5NMe2)][B(C6F5)4] (859157-10-1) → [([2,6-(i)Pr2C6H3NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr2C6H3(fluorobenzene)][B(C6F5)4] (874919-67-2)

Guidance literature:

In fluorobenzene; several recrystns. (C6H5F);

DOI:10.1021/ja0566026

Reference yield: 99.0%

[([2,6-(i)Pr2C6H3NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr2C6H3(fluorobenzene)][B(C6F5)4] (874919-67-2) + diphenyl acetylene (501-65-5) → [([2,6-(i)Pr2C6H3NC((t)Bu)]2CH)TiN(2,6-(i)Pr2C6H3)CPhCPh][B(C6F5)4] (874919-73-0)

Guidance literature:

In not given;

DOI:10.1021/ja0566026

upstream raw materials:

fluorobenzene

([2,6-(i)Pr₂C₆H₃NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr₂C₆H₃(Cl)

triethylsilylium tetrakis(pentafluorophenyl), toluene adduct

[([2,6-(i)Pr2C6H3NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr2C6H3(η1-C6H5NMe2)][B(C6F5)4]

Downstream raw materials:

[([2,6-(i)Pr₂C₆H₃NC((t)Bu)]2CH)TiN(2,6-(i)Pr₂C₆H₃)CPhCPh][B(C₆F₅)4]