C₃₇H₆₀O₅Si

Base Information

Chemical Name:C₃₇H₆₀O₅Si
CAS No.:864152-06-7
Molecular Formula:C₃₇H₆₀O₅Si
Molecular Weight:612.966
Hs Code.:

C<sub>37</sub>H<sub>60</sub>O<sub>5</sub>Si

Synonyms:C₃₇H₆₀O₅Si

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Chemical Property of C₃₇H₆₀O₅Si

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Technology Process of C₃₇H₆₀O₅Si

There total 22 articles about C₃₇H₆₀O₅Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 864152-15-8
C₃₇H₅₇F₃O₈SSi

: 544-97-8
dimethyl zinc(II)

: 864152-06-7
C₃₇H₆₀O₅Si

Guidance literature:: tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 0 - 20 ℃; for 28h;
DOI:10.1055/s-2005-871549

Reference yield:

: 871329-34-9
(3aS,4S,6R,7aR)-4,6,7a-Trimethyl-3a,4,5,6,7,7a-hexahydro-inden-1-one

: 864152-06-7
C₃₇H₆₀O₅Si

Guidance literature:: Multi-step reaction with 14 steps

1.1: 97 percent / tetrahydrofuran / 5 h / -78 - -23 °C

2.1: 77 percent / aq. H₂SO₄ / tetrahydrofuran / 24 h / 0 - 20 °C

3.1: NaH / tetrahydrofuran / 7 h / Heating

3.2: CAN; NaHCO₃ / acetonitrile / 0.33 h / -23 °C

3.3: 70 percent / aq. Dess-Martin periodinane / acetonitrile; CH₂Cl₂ / 39 h / 20 °C

4.1: 95 percent / KHMDS / tetrahydrofuran; hexamethylphosphoric acid triamide / -78 - 20 °C

5.1: 83 percent / toluene / 10 h / Heating

6.1: 91 percent / LiBH₄ / tetrahydrofuran; methanol / 24 h / 0 - 20 °C

7.1: TBAF / tetrahydrofuran / 2 h / 0 - 20 °C

8.1: imidazole / dimethylformamide / 1 h / 20 °C

9.1: LDA; TMSCl / tetrahydrofuran / 3 h / -78 °C

9.2: Pd(OAc)2 / acetonitrile / 10 h / 50 °C

10.1: TBAF / tetrahydrofuran / 2 h / 0 - 20 °C

11.1: 2,6-lutidine / CH₂Cl₂ / 4 h / -78 - -45 °C

12.1: 84 percent / Cu(II)-salicylidene-iminato complex / tetrahydrofuran / 44 h / -45 °C

13.1: MeLi / tetrahydrofuran / 2 h / -78 - 20 °C

13.2: 86 percent / tetrahydrofuran / 16 h / -78 °C

14.1: 95 percent / Pd(PPh₃)4 / tetrahydrofuran / 28 h / 0 - 20 °C

With 1H-imidazole; 2,6-dimethylpyridine; lithium borohydride; chloro-trimethyl-silane; sulfuric acid; tetrabutyl ammonium fluoride; methyllithium; potassium hexamethylsilazane; sodium hydride; lithium diisopropyl amide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; Cu(II)-salicylidene-iminato; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1055/s-2005-871549

Reference yield:

: 864151-96-2
(3aR,4S,6R,7aR)-4,6,7a-Trimethyl-octahydro-inden-1-one

: 864152-06-7
C₃₇H₆₀O₅Si

Guidance literature:: Multi-step reaction with 16 steps

1.1: LDA / tetrahydrofuran / 3 h / -78 °C

1.2: tetrahydrofuran

2.1: allyl carbonate / Pd(OAc)2 / acetonitrile / Heating

3.1: 97 percent / tetrahydrofuran / 5 h / -78 - -23 °C

4.1: 77 percent / aq. H₂SO₄ / tetrahydrofuran / 24 h / 0 - 20 °C

5.1: NaH / tetrahydrofuran / 7 h / Heating

5.2: CAN; NaHCO₃ / acetonitrile / 0.33 h / -23 °C

5.3: 70 percent / aq. Dess-Martin periodinane / acetonitrile; CH₂Cl₂ / 39 h / 20 °C

6.1: 95 percent / KHMDS / tetrahydrofuran; hexamethylphosphoric acid triamide / -78 - 20 °C

7.1: 83 percent / toluene / 10 h / Heating

8.1: 91 percent / LiBH₄ / tetrahydrofuran; methanol / 24 h / 0 - 20 °C

9.1: TBAF / tetrahydrofuran / 2 h / 0 - 20 °C

10.1: imidazole / dimethylformamide / 1 h / 20 °C

11.1: LDA; TMSCl / tetrahydrofuran / 3 h / -78 °C

11.2: Pd(OAc)2 / acetonitrile / 10 h / 50 °C

12.1: TBAF / tetrahydrofuran / 2 h / 0 - 20 °C

13.1: 2,6-lutidine / CH₂Cl₂ / 4 h / -78 - -45 °C

14.1: 84 percent / Cu(II)-salicylidene-iminato complex / tetrahydrofuran / 44 h / -45 °C

15.1: MeLi / tetrahydrofuran / 2 h / -78 - 20 °C

15.2: 86 percent / tetrahydrofuran / 16 h / -78 °C

16.1: 95 percent / Pd(PPh₃)4 / tetrahydrofuran / 28 h / 0 - 20 °C

With 1H-imidazole; 2,6-dimethylpyridine; lithium borohydride; chloro-trimethyl-silane; diallylcarbonate; sulfuric acid; tetrabutyl ammonium fluoride; methyllithium; potassium hexamethylsilazane; sodium hydride; lithium diisopropyl amide; palladium diacetate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; Cu(II)-salicylidene-iminato; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; N,N-dimethyl-formamide; toluene; acetonitrile;
DOI:10.1055/s-2005-871549