Manganese,dodecacarbonyltrihydrotri-, triangulo (9CI)

Base Information

Chemical Name:Manganese,dodecacarbonyltrihydrotri-, triangulo (9CI)
CAS No.:18444-56-9
Molecular Formula:C12H3 Mn3 O12
Molecular Weight:503.963
Hs Code.:

Synonyms:Manganese,dodecacarbonyltrihydrotri-, triangulo- (8CI)

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Chemical Property of Manganese,dodecacarbonyltrihydrotri-, triangulo (9CI)

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MSDS Files:: SDS file from LookChem

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Technology Process of Manganese,dodecacarbonyltrihydrotri-, triangulo (9CI)

There total 1 articles about Manganese,dodecacarbonyltrihydrotri-, triangulo (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 130934-62-2
{As(C6H5)4}2{(μ-H)(Mn3(μ-CO)2(CO)10)}

: 2As(C₆H₅)4⁽¹⁺⁾*(H)Mn₅(CO)17^(2-)=(As(C₆H₅)4)2((H)Mn₅(CO)17)

: 18444-56-9
[Mn3(CO)12(μ-H)3]

Guidance literature:: With AlCl₃; In dichloromethane; addn. of water-free AlCl3 to Mn-complex in CH2Cl2 at room temp. under Ar, colour changes from brown to violet, stirring for 5 min; filtn., concn., chromy., elution (CH2Cl2), first fraction yields H3Mn3(CO)12, second fraction yields product, evapn. of solvent in vac., dissolution (CH3COOEt), filtn., crystn. (4°C), decantation, washing (n-hexane), drying in vac., elem. anal.;
DOI:10.1016/0022-328X(93)80358-I

Reference yield: 61.0%

: 18444-56-9
[Mn3(CO)12(μ-H)3]

: 65423-44-1
(2-diphenylphosphino)benzeneamine

: 928126-83-4
Mn₂(CO)6(Ph₂PC₆H₄NH-2)2

Guidance literature:: In n-heptane; under N2, 2 equiv. of P-compd. was added to the Mn-compd. soln., heatingto 80-90 °C over a period of 50 min; cooling to room temp., evapn. in vac., residue was redissolved in CH2Cl2, similar vol. of Et2O was added, crystn. in a freezer for a week, elem.anal.;
DOI:10.1016/j.poly.2006.06.034

Reference yield: 60.0%

: [Fe2(η5-cyclopentadienyl)2(CO)2(μ-CO)(μ-CCH2)]

: 18444-56-9
[Mn3(CO)12(μ-H)3]

: 10170-69-1
dimanganese decacarbonyl

: [Fe2Mn(CO)3(μ-CO)3(μ3-CMe)(η-C5H5)2]

Guidance literature:: In benzene; under N2, soln. of Mn- and Fe-complexes (molar ratio 1:3) in benzene was heated under reflux, at 15 min intervals further portions of Mn-complex were added up to total 2.3 equiv, refluxed for 1 h (total 3 h); volatiles removed in vac., extd. in toluene, extracts chromd. on alumina column, eluted with toluene, blue-black band collected, solvent removed, recrystd. from THF-light petroleum; elem. anal.;
DOI:10.1039/DT9830001357