Technology Process of Manganese,pentacarbonylhydro-, (OC-6-21)-
There total 58 articles about Manganese,pentacarbonylhydro-, (OC-6-21)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
water;
In
tetrahydrofuran-d8;
to the NMR tube charged with a soln. of complex in THF-d8 at -10°C water was added, 2 h; not sepd., detected by (1)H NMR;
DOI:10.1021/ja00267a015
- Guidance literature:
-
In
tetrahydrofuran;
N2-atmosphere; closed vessel, 48 bar CO/H2, 60°C, 8 h; cooling to room temp., solvent removal (vac.), dissoln. in 25% CH2Cl2/pentane, chromy. (SiO2, 5% CH2Cl2/pentane), evapn., drying (vac.);
DOI:10.1016/S0022-328X(98)00644-5
- Guidance literature:
-
With
sodium amalgam; phosphoric acid;
In
tetrahydrofuran;
Mn2(CO)10 was reacted with Na#Hg in THF; after 2 h filtered and dried and the sodium salt wased with pentane for up to 12 h to remove occluded THF; filtered; vac. dried, and reacted with degassed 85% H3PO4, and distilled onto P2O5; redistilled on a high vac. line and collected in a m-xylene trap (-48°C) to remove any residual THF;
DOI:10.1021/om00120a007
