Manganese,pentacarbonylhydro-, (OC-6-21)-

Base Information

Chemical Name:Manganese,pentacarbonylhydro-, (OC-6-21)-
CAS No.:16972-33-1
Molecular Formula:C5H Mn O5
Molecular Weight:195.998
Hs Code.:
Mol file:16972-33-1.mol

Synonyms:Hydrogenpentacarbonylmanganate(-I) (7CI); Manganese, pentacarbonylhydro- (8CI);Hydridomanganese pentacarbonyl; Hydridopentacarbonylmanganese; Manganesepentacarbonyl hydride; Pentacarbonylhydridomanganese;Pentacarbonylhydromanganese; Pentacarbonylmanganese hydride

Suppliers and Price of Manganese,pentacarbonylhydro-, (OC-6-21)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 8 raw suppliers

Chemical Property of Manganese,pentacarbonylhydro-, (OC-6-21)-

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Manganese,pentacarbonylhydro-, (OC-6-21)-

There total 58 articles about Manganese,pentacarbonylhydro-, (OC-6-21)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 68433-34-1
(CO)5MnCH(C₆H₅)OSi(CH₃)3

: 16972-33-1
pentacarbonylhydridomanganese

: (CO)5MnCH(C₆H₅)OH

: 100-52-7
benzaldehyde

Guidance literature:: With water; In tetrahydrofuran-d8; to the NMR tube charged with a soln. of complex in THF-d8 at -10°C water was added, 2 h; not sepd., detected by (1)H NMR;
DOI:10.1021/ja00267a015

Reference yield: 95.0%

: 159983-78-5
Mn(CO)5(CO(CH₂)10CH₃)

: 201230-82-2
carbon monoxide

: 1333-74-0
hydrogen

: 10170-69-1
dimanganese decacarbonyl

: 16972-33-1
pentacarbonylhydridomanganese

Guidance literature:: In tetrahydrofuran; N2-atmosphere; closed vessel, 48 bar CO/H2, 60°C, 8 h; cooling to room temp., solvent removal (vac.), dissoln. in 25% CH2Cl2/pentane, chromy. (SiO2, 5% CH2Cl2/pentane), evapn., drying (vac.);
DOI:10.1016/S0022-328X(98)00644-5

Reference yield: 80.0%

: 10170-69-1
dimanganese decacarbonyl

: 16972-33-1
pentacarbonylhydridomanganese

Guidance literature:: With sodium amalgam; phosphoric acid; In tetrahydrofuran; Mn2(CO)10 was reacted with Na#Hg in THF; after 2 h filtered and dried and the sodium salt wased with pentane for up to 12 h to remove occluded THF; filtered; vac. dried, and reacted with degassed 85% H3PO4, and distilled onto P2O5; redistilled on a high vac. line and collected in a m-xylene trap (-48°C) to remove any residual THF;
DOI:10.1021/om00120a007