13-O-benzyl-6,7,9,10,11,12-hexadeoxy-1,2:3,4-di-O-isopropylidene-α-D-galacto-tridecopyranos-8-ulose

Base Information

Chemical Name:13-O-benzyl-6,7,9,10,11,12-hexadeoxy-1,2:3,4-di-O-isopropylidene-α-D-galacto-tridecopyranos-8-ulose
CAS No.:141177-16-4
Molecular Formula:C₂₆H₃₈O₇
Molecular Weight:462.584
Hs Code.:

Synonyms:13-O-benzyl-6,7,9,10,11,12-hexadeoxy-1,2:3,4-di-O-isopropylidene-α-D-galacto-tridecopyranos-8-ulose

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Chemical Property of 13-O-benzyl-6,7,9,10,11,12-hexadeoxy-1,2:3,4-di-O-isopropylidene-α-D-galacto-tridecopyranos-8-ulose

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Technology Process of 13-O-benzyl-6,7,9,10,11,12-hexadeoxy-1,2:3,4-di-O-isopropylidene-α-D-galacto-tridecopyranos-8-ulose

There total 5 articles about 13-O-benzyl-6,7,9,10,11,12-hexadeoxy-1,2:3,4-di-O-isopropylidene-α-D-galacto-tridecopyranos-8-ulose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 141177-15-3
13-O-benzyl-6,7,9,10,11,12-hexadeoxy-1,2:3,4-di-O-isopropylidene-DL-glycero-α-D-galacto-tridecopyranose

: 141177-16-4
13-O-benzyl-6,7,9,10,11,12-hexadeoxy-1,2:3,4-di-O-isopropylidene-α-D-galacto-tridecopyranos-8-ulose

Guidance literature:: With pyridine; pyridinium chlorochromate; In dichloromethane;
DOI:10.1016/0008-6215(92)80040-8

Reference yield:

: 1014-93-3
1-(benzyloxy)-5-bromopentane

: 141177-16-4
13-O-benzyl-6,7,9,10,11,12-hexadeoxy-1,2:3,4-di-O-isopropylidene-α-D-galacto-tridecopyranos-8-ulose

Guidance literature:: Multi-step reaction with 2 steps

1: 1) Mg / 1) ether, 2) ether, 15 min

2: 74 percent / pyridinium chlorochromate, pyridine / CH₂Cl₂

With pyridine; magnesium; pyridinium chlorochromate; In dichloromethane;
DOI:10.1016/0008-6215(92)80040-8

Reference yield:

: 4541-15-5
5-(benzyloxy)-1-pentanol

: 141177-16-4
13-O-benzyl-6,7,9,10,11,12-hexadeoxy-1,2:3,4-di-O-isopropylidene-α-D-galacto-tridecopyranos-8-ulose

Guidance literature:: Multi-step reaction with 4 steps

1: 75 percent / pyridine / 0 °C

2: 60 percent / lithium bromide / acetone / 2 h / Heating

3: 1) Mg / 1) ether, 2) ether, 15 min

4: 74 percent / pyridinium chlorochromate, pyridine / CH₂Cl₂

With pyridine; magnesium; pyridinium chlorochromate; lithium bromide; In dichloromethane; acetone;
DOI:10.1016/0008-6215(92)80040-8