Technology Process of 2-(2,5-bis(2,5,8,11,15,18,21,24-octaoxapentacosan-13-yloxy)-4-iodophenyl)-1,3-dioxolane
There total 3 articles about 2-(2,5-bis(2,5,8,11,15,18,21,24-octaoxapentacosan-13-yloxy)-4-iodophenyl)-1,3-dioxolane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
tetra-N-butylammonium tribromide; orthoformic acid triethyl ester;
at 20 ℃;
for 72h;
DOI:10.1021/jo501129d
- Guidance literature:
-
Multi-step reaction with 4 steps
1: iodine; silver nitrate / methanol / 20 °C
2: boron tribromide / dichloromethane / -78 - 20 °C
3: potassium carbonate / N,N-dimethyl-formamide / 48 h / 75 °C / Schlenk technique
4: orthoformic acid triethyl ester; tetra-N-butylammonium tribromide / 72 h / 20 °C
With
iodine; tetra-N-butylammonium tribromide; boron tribromide; potassium carbonate; silver nitrate; orthoformic acid triethyl ester;
In
methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo501129d
- Guidance literature:
-
Multi-step reaction with 3 steps
1: boron tribromide / dichloromethane / -78 - 20 °C
2: potassium carbonate / N,N-dimethyl-formamide / 48 h / 75 °C / Schlenk technique
3: orthoformic acid triethyl ester; tetra-N-butylammonium tribromide / 72 h / 20 °C
With
tetra-N-butylammonium tribromide; boron tribromide; potassium carbonate; orthoformic acid triethyl ester;
In
dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo501129d
