((2S,3S)-3-((2S,3S,4S)-5-[(1,1-dimethylethyl)diphenylsilyloxy]-4-methyl-3-(triethylsilyloxy)pentan-2-yl)oxiran-2-yl)methanol

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Chemical Name:((2S,3S)-3-((2S,3S,4S)-5-[(1,1-dimethylethyl)diphenylsilyloxy]-4-methyl-3-(triethylsilyloxy)pentan-2-yl)oxiran-2-yl)methanol
CAS No.:1229345-53-2
Molecular Formula:C₃₁H₅₀O₄Si₂
Molecular Weight:542.907
Hs Code.:

Synonyms:((2S,3S)-3-((2S,3S,4S)-5-[(1,1-dimethylethyl)diphenylsilyloxy]-4-methyl-3-(triethylsilyloxy)pentan-2-yl)oxiran-2-yl)methanol

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Chemical Property of ((2S,3S)-3-((2S,3S,4S)-5-[(1,1-dimethylethyl)diphenylsilyloxy]-4-methyl-3-(triethylsilyloxy)pentan-2-yl)oxiran-2-yl)methanol

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Technology Process of ((2S,3S)-3-((2S,3S,4S)-5-[(1,1-dimethylethyl)diphenylsilyloxy]-4-methyl-3-(triethylsilyloxy)pentan-2-yl)oxiran-2-yl)methanol

There total 1 articles about ((2S,3S)-3-((2S,3S,4S)-5-[(1,1-dimethylethyl)diphenylsilyloxy]-4-methyl-3-(triethylsilyloxy)pentan-2-yl)oxiran-2-yl)methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1229345-67-8
(4S,5R,6S,E)-7-[(1,1-dimethylethyl)diphenylsilyloxy]-4,6-dimethyl-5-(triethylsilyloxy)-hept-2-en-1-ol

: 1229345-53-2
((2S,3S)-3-((2S,3S,4S)-5-[(1,1-dimethylethyl)diphenylsilyloxy]-4-methyl-3-(triethylsilyloxy)pentan-2-yl)oxiran-2-yl)methanol

Guidance literature:: With titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate; In decane; dichloromethane; at -25 - -20 ℃; for 14.25h; stereoselective reaction; Inert atmosphere; Molecular sieve;
DOI:10.1021/ol100985n

Reference yield: 83.0%

: 1229345-53-2
((2S,3S)-3-((2S,3S,4S)-5-[(1,1-dimethylethyl)diphenylsilyloxy]-4-methyl-3-(triethylsilyloxy)pentan-2-yl)oxiran-2-yl)methanol

: 917-54-4
methyllithium

: 1229345-59-8
(2R,3R,4S,5S,6S)-7-[(1,1-dimethylethyl)diphenylsilyloxy]-2,4,6-trimethyl-5-(triethylsilyloxy)heptane-1,3-diol

Guidance literature:: methyllithium; With copper(l) iodide; In tetrahydrofuran; diethyl ether; at 0 ℃; Inert atmosphere;

((2S,3S)-3-((2S,3S,4S)-5-[(1,1-dimethylethyl)diphenylsilyloxy]-4-methyl-3-(triethylsilyloxy)pentan-2-yl)oxiran-2-yl)methanol; In tetrahydrofuran; diethyl ether; at -15 - 0 ℃; Inert atmosphere;

With water; ammonium chloride; In tetrahydrofuran; diethyl ether; Inert atmosphere;
DOI:10.1021/ol100985n