[3-((E)-2-Tributylstannanyl-vinyl)-phenyl]-carbamic acid tert-butyl ester

Base Information

• Chemical Name: [3-((E)-2-Tributylstannanyl-vinyl)-phenyl]-carbamic acid tert-butyl ester
• CAS No.: 185619-68-5
• Molecular Formula: C₂₅H₄₃NO₂Sn
• Molecular Weight: 508.332
• Mol file: 185619-68-5.mol

Synonyms:[3-((E)-2-Tributylstannanyl-vinyl)-phenyl]-carbamic acid tert-butyl ester

Chemical Property of [3-((E)-2-Tributylstannanyl-vinyl)-phenyl]-carbamic acid tert-butyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [3-((E)-2-Tributylstannanyl-vinyl)-phenyl]-carbamic acid tert-butyl ester

There total 2 articles about [3-((E)-2-Tributylstannanyl-vinyl)-phenyl]-carbamic acid tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

tri-n-butyl-tin hydride (688-73-3) + (3-ethynyl-phenyl)-carbamic acid tert-butyl ester (185619-66-3) → [3-((E)-2-Tributylstannanyl-vinyl)-phenyl]-carbamic acid tert-butyl ester (185619-68-5)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); In not given; 100°C, 2 h;

DOI:10.1039/cc9960002647

Reference yield: 52.0%

(E)-1,2-bis(tri-n-butylstannyl)ethene (14275-61-7,15979-38-1,118855-16-6) + iodo-3-(tert-butyloxycarbonylamino)benzene (143390-49-2) → [3-((E)-2-Tributylstannanyl-vinyl)-phenyl]-carbamic acid tert-butyl ester (185619-68-5)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; 100°C;

DOI:10.1039/cc9960002647

Reference yield: 70.0%

(2E,4E)-5-Bromo-penta-2,4-dienoic acid (2-hydroxy-5-oxo-cyclopent-1-enyl)-amide (182158-34-5) + [3-((E)-2-Tributylstannanyl-vinyl)-phenyl]-carbamic acid tert-butyl ester (185619-68-5) → {3-[(1E,3E,5E)-6-(2-Hydroxy-5-oxo-cyclopent-1-enylcarbamoyl)-hexa-1,3,5-trienyl]-phenyl}-carbamic acid tert-butyl ester

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; diisobutylaluminium hydride; In tetrahydrofuran; N,N-dimethyl-formamide; for 12h; Ambient temperature;

DOI:10.1016/S0040-4020(98)00536-5

upstream raw materials:

(E)-1,2-bis(tri-n-butylstannyl)ethene

iodo-3-(tert-butyloxycarbonylamino)benzene

tri-n-butyl-tin hydride

(3-ethynyl-phenyl)-carbamic acid tert-butyl ester