(2R,3R)-2-Methyl-3-[4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyloxy)-benzyloxy]-butyraldehyde

Base Information

Chemical Name:(2R,3R)-2-Methyl-3-[4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyloxy)-benzyloxy]-butyraldehyde
CAS No.:780773-41-3
Molecular Formula:C₂₁H₂₁F₁₃O₃
Molecular Weight:568.375
Hs Code.:

Synonyms:(2R,3R)-2-Methyl-3-[4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyloxy)-benzyloxy]-butyraldehyde

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Chemical Property of (2R,3R)-2-Methyl-3-[4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyloxy)-benzyloxy]-butyraldehyde

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Technology Process of (2R,3R)-2-Methyl-3-[4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyloxy)-benzyloxy]-butyraldehyde

There total 5 articles about (2R,3R)-2-Methyl-3-[4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyloxy)-benzyloxy]-butyraldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 780773-49-1
(2S,3R)-2-Methyl-3-[4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyloxy)-benzyloxy]-butan-1-ol

: 780773-41-3
(2R,3R)-2-Methyl-3-[4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyloxy)-benzyloxy]-butyraldehyde

Guidance literature:: With Dess-Martin periodane; In dichloromethane; at 20 ℃; for 3h;
DOI:10.1021/jo051526a

Reference yield:

: 780773-39-9
(2R,3S)-2-methyl-1,3-bis(trimethylsilanyloxy)butane

: 780773-41-3
(2R,3R)-2-Methyl-3-[4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyloxy)-benzyloxy]-butyraldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: 81 percent / trimethylsilyl triflate / CH₂Cl₂ / 12 h / -78 °C

2: DIBAL / CH₂Cl₂; hexane / 3 h / 0 °C

3: Dess-Martin periodinane / CH₂Cl₂ / 3 h / 20 °C

With trimethylsilyl trifluoromethanesulfonate; diisobutylaluminium hydride; Dess-Martin periodane; In hexane; dichloromethane; 1: Noyori ketalization / 3: Dess-Martin oxidation;
DOI:10.1021/jo051526a

Reference yield:

: 780772-20-5
(4R,5S)-4,5-dimethyl-2-[4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyloxy)phenyl]-[1,3]dioxane

: 780773-41-3
(2R,3R)-2-Methyl-3-[4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyloxy)-benzyloxy]-butyraldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: DIBAL / CH₂Cl₂; hexane / 3 h / 0 °C

2: Dess-Martin periodinane / CH₂Cl₂ / 3 h / 20 °C

With diisobutylaluminium hydride; Dess-Martin periodane; In hexane; dichloromethane; 2: Dess-Martin oxidation;
DOI:10.1021/jo051526a