1-benzyloxy-(7R)-7-(methoxymethoxy)-3-tridecyne

Base Information

Chemical Name:1-benzyloxy-(7R)-7-(methoxymethoxy)-3-tridecyne
CAS No.:181211-29-0
Molecular Formula:C₂₂H₃₄O₃
Molecular Weight:346.51
Hs Code.:

Synonyms:1-benzyloxy-(7R)-7-(methoxymethoxy)-3-tridecyne

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Chemical Property of 1-benzyloxy-(7R)-7-(methoxymethoxy)-3-tridecyne

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Technology Process of 1-benzyloxy-(7R)-7-(methoxymethoxy)-3-tridecyne

There total 6 articles about 1-benzyloxy-(7R)-7-(methoxymethoxy)-3-tridecyne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 22273-77-4
((but-3-yn-1-yloxy)methyl)benzene

: 181211-28-9
1-bromo-(3R)-3-(methoxymethoxy)nonane

: 181211-29-0
1-benzyloxy-(7R)-7-(methoxymethoxy)-3-tridecyne

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; In tetrahydrofuran; hexane; at -78 - 0 ℃; for 4.5h;
DOI:10.1016/S0040-4020(98)00484-0

Reference yield:

: 181211-26-7
(3R)-3-(methoxymethoxy)-1-nonanol

: 181211-29-0
1-benzyloxy-(7R)-7-(methoxymethoxy)-3-tridecyne

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / CBr₄; Ph₃P / CH₂Cl₂ / 0.5 h / 0 °C

2: 83 percent / n-BuLi; HMPA / tetrahydrofuran; hexane / 4.5 h / -78 - 0 °C

With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; carbon tetrabromide; triphenylphosphine; In tetrahydrofuran; hexane; dichloromethane; 1: Bromination / 2: Addition;
DOI:10.1016/S0040-4020(98)00484-0

Reference yield:

: 181210-33-3
ethyl (3R)-3-(methoxymethoxy)nonanethioate

: 181211-29-0
1-benzyloxy-(7R)-7-(methoxymethoxy)-3-tridecyne

Guidance literature:: Multi-step reaction with 3 steps

1: 98 percent / LAH / tetrahydrofuran / 1.5 h / 0 - 20 °C

2: 92 percent / CBr₄; Ph₃P / CH₂Cl₂ / 0.5 h / 0 °C

3: 83 percent / n-BuLi; HMPA / tetrahydrofuran; hexane / 4.5 h / -78 - 0 °C

With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium aluminium tetrahydride; n-butyllithium; carbon tetrabromide; triphenylphosphine; In tetrahydrofuran; hexane; dichloromethane; 1: Reduction / 2: Bromination / 3: Addition;
DOI:10.1016/S0040-4020(98)00484-0