(-)589-cis-((R)-dimethyl(1-ethyl-α-naphthyl)aminato-C(2)N)((R)-methylphenyl(8-quinolyl)phosphine)palladium(II) hexafluorophosphate

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Chemical Name:(-)589-cis-((R)-dimethyl(1-ethyl-α-naphthyl)aminato-C(2)N)((R)-methylphenyl(8-quinolyl)phosphine)palladium(II) hexafluorophosphate
CAS No.:80226-02-4
Molecular Formula:C₃₀H₃₀N₂PPd*F₆P
Molecular Weight:700.94
Hs Code.:

Synonyms:(-)589-cis-((R)-dimethyl(1-ethyl-α-naphthyl)aminato-C(2)N)((R)-methylphenyl(8-quinolyl)phosphine)palladium(II) hexafluorophosphate

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Chemical Property of (-)589-cis-((R)-dimethyl(1-ethyl-α-naphthyl)aminato-C(2)N)((R)-methylphenyl(8-quinolyl)phosphine)palladium(II) hexafluorophosphate

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Technology Process of (-)589-cis-((R)-dimethyl(1-ethyl-α-naphthyl)aminato-C(2)N)((R)-methylphenyl(8-quinolyl)phosphine)palladium(II) hexafluorophosphate

There total 1 articles about (-)589-cis-((R)-dimethyl(1-ethyl-α-naphthyl)aminato-C(2)N)((R)-methylphenyl(8-quinolyl)phosphine)palladium(II) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: ammonium hexafluorophosphate

: (R_c)-di-μ-chloro-bis[1-(1'-dimethylaminoethyl)-2-naphthyl-C,N]dipalladium(ii)

: 78-93-3
butanone

: 80127-37-3,80183-97-7,80183-96-6
8-methyl(phenyl)phosphino-quinoline

: 80226-02-4
(-)589-cis-((R)-dimethyl(1-ethyl-α-naphthyl)aminato-C(2)N)((R)-methylphenyl(8-quinolyl)phosphine)palladium(II) hexafluorophosphate

: (+)589-cis-((R)-dimethyl(1-ethyl-α-naphthyl)aminato-C(2)N)((S)-methylphenyl(8-quinolyl)phosphine)palladium(II) hexafluorophosphate-ethyl methyl ketone solvate

Guidance literature:: In methanol; water; under Ar atm. mixt. (R,S)-methylphenyl(8-quinolyl)phosphine and dichloro-bis((R)-dimethyl(1-ethylα-naphthyl)aminato)dipalladium in methanol stirred until solids dissolved, filtered and excess NH4PF6 in water added; ptt. separated, washed with water, aq. MeOH (1:1), MeOH-Et2O and dried in vacuo, diastereisomers separated by fractional recrystn.: (R,R)-isomer from boiling acetone and (R,S)-isomer from boiling ethyl methyl ketone; elem. anal.;

Reference yield: 85.0%

: 80226-02-4
(-)589-cis-((R)-dimethyl(1-ethyl-α-naphthyl)aminato-C(2)N)((R)-methylphenyl(8-quinolyl)phosphine)palladium(II) hexafluorophosphate

: 80145-82-0
(+)589-dichloro((R)-methylphenyl(8-quinolyl)phosphine)palladium(II)

Guidance literature:: With lithium chloride; In sulfuric acid; under Ar atm. cis-((R)-dimethyl(1-ethyl-α-naphthyl)aminato)((R)-methylphenyl(8-quinolyl)phosphine)palladium(II) hexafluorophosphate dissolved in 70% sulfuric acid, soln. poured on to ice, LiCl added and mixt. stirred; soln. extd. with dichloromethane, org. layer separated and dried over MgSO4, solvent removed, product recrystd. from boiling methanol; elem. anal.;